2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE

2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE Basic information
Product Name:2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE
Synonyms:Trifluoromethanesulfonic Acid 2-(Trimethylsilyl)phenyl Ester;2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE;2-(trimethylsilyl)phenyl trifluoromethane-sulfona;2-(Trimethylsilyl)phenyl Triflate Trifluoromethanesulfonic Acid 2-(Trimethylsilyl)phenyl Ester;(TriMethylsilyl)phenyl Triflate;TriMethylsilyl)phenyl trifluoroMethanesulfona;2-(TriMethylsilyl)phenyl trifluoroMethanesulfonate 97%;2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFOTE
CAS:88284-48-4
MF:C10H13F3O3SSi
MW:298.35
EINECS:
Product Categories:Si (Classes of Silicon Compounds);Si-(C)4 Compounds;Silicon Compounds (for Synthesis);Synthetic Organic Chemistry;Organic Triflates;Organic Building Blocks;Sulfur Compounds
Mol File:88284-48-4.mol
2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE Structure
2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE Chemical Properties
Boiling point 70 °C/2 mmHg (lit.)
density 1.229 g/mL at 25 °C (lit.)
refractive index n20/D 1.456(lit.)
Fp 205 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form clear liquid
color Colorless to Light yellow
Specific Gravity1.229
Hydrolytic Sensitivity7: reacts slowly with moisture/water
InChIKeyXBHPFCIWRHJDCP-UHFFFAOYSA-N
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 26-27-36/37/39-45
RIDADR UN 3265 8/PG 2
WGK Germany 3
HazardClass 8
PackingGroup 
HS Code 29319090
MSDS Information
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SigmaAldrich English
2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE Usage And Synthesis
Physical propertiesbp 70 °C/2 mmHg; d 1.229 g mL?1
Uses2-(Trimethylsilyl)phenyl trifluoromethanesulfonate may be used to generate benzyne under mild conditions of simple fluoride treatment at room temperature.
Uses2-(Trimethylsilyl)phenyl Triflate is a useful reagent applied in reactions of Polycyclic Arenes, Heteroatom Arylation,Heteroarenes and Benzannulated Heterocycles, Carbon Arylations, etc.	2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE
General Description2-(Trimethylsilyl)phenyl trifluoromethanesulfonate is an important ortho-benzyne precursor in aryne chemistry.
4-METHOXY-2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE,4-METHOXY-2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE,95.0+%(GC) 3-METHOXY-2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE,95.0+%(GC),3-Methoxy-2-(trimethylsilyl)phenyl Trifluoromethanesulfonate 1-(TRIMETHYLSILYL)-2-NAPHTHYL TRIFLATE 3,3''-BIS-(TRIMETHYLSILYL)BIPHENYL-4,4''-DIYL BIS(TRIFLUOROMETHANESULFONATE) Phenyl trifluoromethanesulfonate 2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE 3-(TRIMETHYLSILYL)-2-NAPHTHYL TRIFLUOROMETHANESULFONATE 1,3,5-TRIS[4-(TRIFLUOROMETHANESULFONYLOXY)-3-(TRIMETHYLSILYL)PHENYL]BENZENE Trifluoromethane 2-METHYL-6-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE,96.0+%(GC),2-METHYL-6-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE 4-METHYL-2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE,4-METHYL-2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE,98.0+%(GC)

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