(+)-MENTHYL CHLOROFORMATE

(+)-MENTHYL CHLOROFORMATE Basic information
Product Name:(+)-MENTHYL CHLOROFORMATE
Synonyms:(+)-MENTHYL CHLOROFORMATE;2-isopropyl-5-Methylcyclohexyl carbonochloridate;(1S,2R,5S)-(+)-2-Isopropyl-5-methylcyclohex-1-yl chloroformate, (1S,2R,5S)-(+)-5-Methyl-2-(prop-2-yl)cyclohex-1-yl carbonochloridoate;(1S)-(+)-Menthyl chloroforMate optical purity ee: 97% (GLC);Carbonochloridic acid,5-methyl-2-(1-methylethyl)cyclohexyl ester, (1S,2R,5S)-;(+)-Menthyl chloroformate,97%;(R)-(-)-Menthyl Chloroformate;(1S)-(+)-Menthylchloroformate,97%
CAS:7635-54-3
MF:C11H19ClO2
MW:218.72
EINECS:
Product Categories:chiral;Biochemistry;for Resolution of Alcohols & Thiols;for Resolution of Bases;Monocyclic Monoterpenes;Optical Resolution;Synthetic Organic Chemistry;Terpenes;Acid HalidesAsymmetric Synthesis;Chiral Resolving ReagentsDerivatization Reagents;Chiral Building Blocks;Chiral Resolution Reagents;Derivatization Reagents HPLC;Organic Building Blocks;UV-VIS
Mol File:7635-54-3.mol
(+)-MENTHYL CHLOROFORMATE Structure
(+)-MENTHYL CHLOROFORMATE Chemical Properties
Boiling point 108-109 °C11 mm Hg(lit.)
density 1.031 g/mL at 25 °C(lit.)
refractive index n20/D 1.458(lit.)
Fp 158 °F
storage temp. 2-8°C
solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
form clear liquid
color Colorless to Almost colorless
optical activity[α]20/D +83°, c = 1 in chloroform
BRN 2414685
CAS DataBase Reference7635-54-3(CAS DataBase Reference)
Safety Information
Hazard Codes T,C
Risk Statements 23-34-20/21/22
Safety Statements 26-36/37/39-45-25
RIDADR UN 3277 6.1/PG 2
WGK Germany 3
10-19-21
HazardClass 6.1(a)
PackingGroup II
HS Code 29159000
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
(+)-MENTHYL CHLOROFORMATE Usage And Synthesis
Chemical PropertiesColorless to light yellow liqui
UsesChiral auxiliary in the asymmetric synthesis of quaternary carbon centers.
(+)-MENTHYL CHLOROFORMATE Preparation Products And Raw materials
Preparation ProductsIsoprocarb-->Molinate-->Cefotiam-->Propylene carbonate-->Fenobucarb-->XMC-->1-N-Ethoxycarbonyl-3-pyrrolidone-->N-[menthyloxycarbonyl]-L-leucine
CHLOROFORMIC ACID N-OCTYL ESTER 2-Ethylhexyl chloroformate (+)-CHLOROMETHYL MENTHYL ETHER CHLOROMETHYL ISO-PROPYL ETHER Butyl chloroformate HEXYL CHLOROFORMATE Z-Menthyl chloroformate (+)-MENTHYL CHLOROFORMATE Isopropyl chloroformate CHLOROMETHYL OCTYL ETHER Ethyl chloroformate Heptyl chloroformate Isobutyl chloroformate sec-Butyl chloroformate Pentyl chloroformate CHLOROMETHYL CYCLOHEXYL ETHER Cyclohexyl chloroformate Propyl chloroformate

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