Tetraethylene glycol dimethyl ether

Tetraethylene glycol dimethyl ether Basic information
Product Name:Tetraethylene glycol dimethyl ether
Synonyms:TETRA(ETHYLENE GLYCOL) DIMETHYL ETHER, 9 9+%;TETRAETHYLENE GLYCOL DIMETHYL ETHER,STAN DARD FOR GC;Tetraethylene glycol dimethyl ether, 98+%;2,5,8,11,14-Pentaoxapentadecane, Bis[2-(2-methoxyethoxy)ethyl] ether, Dimethoxytetraethylene glycol, Dimethyltetraglycol, Tetraglyme;Tetraethylene glycol dimethyl ether, 99%, extra pure;Tetraethylene glycol dimethyl ether, extra pure;1-(2-methoxyethoxy)-2-[2-(2-methoxyethoxy)-ethoxy]-ethane;1,11-dimethoxy-3,6,9-trioxa-undecane
CAS:143-24-8
MF:C10H22O5
MW:222.28
EINECS:205-594-7
Product Categories:Aliphatics;Alkyl;Biomaterials;Crosslinking Agents;Homobifunctional PEGs;Materials Science;Poly(ethylene glycol) and Poly(ethylene oxide);Polymer Science;Polymers;Building Blocks;C10;Chemical Synthesis;Ethers;Organic Building Blocks;Oxygen Compounds
Mol File:143-24-8.mol
Tetraethylene glycol dimethyl ether Structure
Tetraethylene glycol dimethyl ether Chemical Properties
Melting point -30 °C (lit.)
Boiling point 275-276 °C (lit.)
density 1.009 g/mL at 25 °C (lit.)
vapor density 7.7 (vs air)
vapor pressure <0.01 mm Hg ( 20 °C)
refractive index n20/D 1.432(lit.)
Fp 285 °F
storage temp. Store below +30°C.
solubility Chloroform (Sparingly), Methanol (Slightly)
form Liquid
Specific Gravity1.01
color Clear
explosive limit0.8%(V)
Water Solubility Soluble
Merck 14,9208
BRN 1760005
InChIKeyZUHZGEOKBKGPSW-UHFFFAOYSA-N
LogP-0.84 at 23℃
CAS DataBase Reference143-24-8(CAS DataBase Reference)
NIST Chemistry ReferenceCH3O[CH2CH2O]4CH3(143-24-8)
EPA Substance Registry SystemTetraglyme (143-24-8)
Safety Information
Hazard Codes Xi
Risk Statements 19-43-62-61
Safety Statements 36-24-45-36/37-53-26
WGK Germany 1
RTECS SB0400000
Autoignition Temperature510 °F
TSCA Yes
HS Code 2909 19 90
ToxicityLD50 orally in rats: 5.14 g/kg (Smyth)
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Tetraethylene glycol dimethyl ether Usage And Synthesis
Chemical Propertiesclear liquid
UsesTetraethylene glycol dimethyl ether is used as a solvent.
UsesSolvent.
UsesTetraethylene glycol dimethyl ether is used in lithium-ion battery technology. It is associated with trifluoroethanol and used as a working pair for organic absorption heat pumps. It acts as a solvent for cleaning and degreasing due to its chemical and thermal stability. Moreover, it is suitable solvent for high temperature reactions due its high boiling point. Further, it is used in the selective adsorption of proteins during the promotion of cell adhesion.
DefinitionChEBI: Tetraglyme is a polyether.
General DescriptionTetraethylene glycol dimethyl ether or tetraglyme is an organic aprotic colourless solvent with film forming ability.
Flammability and ExplosibilityNonflammable
Safety ProfileMildly toxic by ingestion. Experimental reproductive effects. An eye irritant. Many glycol ethers are suspected of having dangerous human reproductive effects. When heated to decomposition it emits acrid smoke and irritating fumes. See also GLYCOL ETHERS
Purification MethodsStand the ether over CaH2, LiAlH4 or sodium, and distil it when required. [Beilstein 1 IV 2404.]
Tetraethylene glycol dimethyl ether Preparation Products And Raw materials
Isosorbide dimethyl ether Dacthal Ethanol Polyethylene glycol dimethyl ether ETHANE Diethylene Glycol Dimethyl Ether Ethylbenzene Ethylparaben 1,2-Dimethoxybenzene ISOXADIFEN-ETHYL Diethyl ether Ethyl acetate Bis[2-(2-hydroxyethoxy)ethyl] ether Dimethyl sulfoxide Dimethyl carbonate DME 2-Butoxyethanol Dimethyl sulfate Tetraglyme

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