Bis(2-nitrophenyl) disulfide

Bis(2-nitrophenyl) disulfide Basic information
Product Name:Bis(2-nitrophenyl) disulfide
Synonyms:O-NITROPHENYLDISULFIDE;O,O'-DINITROPHENYL DISULFIDE;Bis-(2-nitrophenyl)-disulfid;Disulfide, bis(2-nitrophenyl);Disulfide, bis(o-nitrophenyl);Disulfide,bis(2-nitrophenyl);o,o'-Dinitrodiphenyl disulfide;1-Nitro-2-[(2-nitrophenyl)disulfanyl]benzene
CAS:1155-00-6
MF:C12H8N2O4S2
MW:308.33
EINECS:214-581-5
Product Categories:
Mol File:1155-00-6.mol
Bis(2-nitrophenyl) disulfide Structure
Bis(2-nitrophenyl) disulfide Chemical Properties
Melting point 194-197 °C (lit.)
Boiling point 441.9±30.0 °C(Predicted)
density 1.62 g/cm3 (-123.16℃)
refractive index 1.6510 (estimate)
storage temp. Sealed in dry,Room Temperature
form powder to crystal
color Light yellow to Brown
BRN 1016770
CAS DataBase Reference1155-00-6(CAS DataBase Reference)
NIST Chemistry ReferenceBis(o-nitrophenyl)disulfide(1155-00-6)
EPA Substance Registry SystemDisulfide, bis(2-nitrophenyl) (1155-00-6)
Safety Information
Safety Statements 22-24/25
WGK Germany 3
TSCA Yes
HS Code 29309099
MSDS Information
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Bis(2-nitrophenyl) disulfide Usage And Synthesis
Chemical Propertiesyellow to yellow-green crystalline powder
UsesBis(o-Nitrophenyl) Disulfide, can be used in a PVC membrane electrode as a sensor for zinc ions. It is also a building block used for the synthesis of various pharmaceutical compounds. It can be used for the preparation of a series of 4-Azaindole inhibitors of c-Met kinase.
General DescriptionPVC membrane electrode based on bis(2-nitrophenyl)disulfide carrier acts as sensor for zinc ions. Bis(2-nitrophenyl) disulphide undergoes mechanochemical grinding with bis(4-chlorophenyl)disulfide in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene catalyst via metathesis reaction to yield non-symmetrical heterodimer 4-chlorophenyl-2′-nitrophenyl disulfide.
Purification MethodsPurify the disulfide by recrystallisation from glacial AcOH or from *C6H6 and the yellow needles are dried in an oven at 100o until the odour of the solvent is absent. It is sparingly soluble in EtOH and Me2CO. [Bogert & Stull Org Synth Coll Vol I 220 1941, Bauer & Cymerman J Chem Soc 3434 1949, Beilstein 6 IV 1672.]
Bis(2-nitrophenyl) disulfide Preparation Products And Raw materials
Raw materialsSodium sulfide-->2-Nitrochlorobenzene-->2-NITROTHIOPHENOL
Preparation Products2-Nitrobenzenesulfonyl chloride-->2,2'-Diaminodiphenyl disulphide-->2-[(DIFLUOROMETHYL)SULFONYL]ANILINE HYDROCHLORIDE
Bis(3-nitrophenyl) disulfide, Nitrophenide,BIS(4-NITROPHENYL) DISULFIDE,BIS(M-NITROPHENYL) DISULFIDE,BIS(P-NITROPHENYL) DISULFIDE,BIS(3-NITROPHENYL) DISULFIDE BIS(4-NITROPHENYL) DISULFIDE,BIS(P-NITROPHENYL) DISULFIDE,Bis(4-nitrophenyl) disulfide, Bis(p-Nitrophenyl) disulfide 2,2'-DINITRO-4,4'-DICHLORO DIPHENYL DISUFIDE Phenylacetone DIPHENYL DISULFIDE BIS(2,4-DINITROPHENYL) DISULFIDE BIS(2-NITRO-4-METHOXYPHENYL)DISULFIDE 1-PHENYL-2-PROPANOL Bis(2-nitrophenyl) disulfide GGKPDLRPCHPPCHYIPRPKPR 2-NITRO-P-TOLYL DISULFIDE SALOR-INT L202053-1EA 3,4-Difluoronitrobenzene 1-Phenyl-2-nitropropene Nitrophenyl 2,4-Dinitrofluorobenzene Thiamine disulfide 1,3-Dinitrobenzene

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