2-Bromopropionyl bromide

2-Bromopropionyl bromide Basic information
Product Name:2-Bromopropionyl bromide
Synonyms:2-Bromopropanoyl bromide;2-bromo-propanoylbromid;2-bromo-Propanoylbromide;-Bromopropionylbromide;Propanoyl bromide, 2-bromo-;2-BROMOPROPIONYL BROMIDE (ALPHA-);2-Bromopropiomyl bromide;2-BROMOPROPIONYL BROMIDE 98.5%
CAS:563-76-8
MF:C3H4Br2O
MW:215.87
EINECS:209-261-7
Product Categories:Acid Halides;Carbonyl Compounds;Organic Building Blocks
Mol File:563-76-8.mol
2-Bromopropionyl bromide Structure
2-Bromopropionyl bromide Chemical Properties
Boiling point 48-50 °C/10 mmHg (lit.)
density 2.061 g/mL at 25 °C (lit.)
vapor density 7.5 (vs air)
vapor pressure 1.3 mm Hg ( 20 °C)
refractive index n20/D 1.518(lit.)
Fp >230 °F
solubility Miscible with trichloromethane, diethyl ether, benzene and acetone.
form clear liquid
color Colorless to Light yellow to Light orange
Specific Gravity2.061
Sensitive Moisture Sensitive
BRN 1071331
Stability:Moisture Sensitive
InChIKeyILLHORFDXDLILE-UHFFFAOYSA-N
LogP0.38 at 25℃
CAS DataBase Reference563-76-8(CAS DataBase Reference)
NIST Chemistry Reference2-Bromopropionyl bromide(563-76-8)
EPA Substance Registry SystemPropanoyl bromide, 2-bromo- (563-76-8)
Safety Information
Hazard Codes C
Risk Statements 22-34
Safety Statements 26-36/37/39-45
RIDADR UN 3265 8/PG 2
WGK Germany 3
TSCA Yes
HazardClass 8
PackingGroup II
HS Code 29159000
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
2-Bromopropionyl bromide Usage And Synthesis
Chemical PropertiesLight yellow liquid
Uses2-Bromopropionyl bromide has been used in the synthesis of:
  • cellulose macroinitiator via direct acylation of cellulose in ionic liquid 1-allyl-3-methylimidazolium chloride
  • 3-(2-bromopropionyl)-2-oxazolidone derivatives
  • bromoester terminated poly(3-hexylthiophene), used as macroinitiator for atom transfer radical polymerization of acrylates.
Uses2-Bromopropionyl bromide is used in the preparation of cellulose macroinitiator through direct acylation of cellulose in ionic liquid 1-allyl-3-methylimidazolium chloride. It is also used to prepare 3-(2-bromopropionyl)-2-oxazolidone derivatives and bromoester terminated poly(3-hexylthiophene). Further, it is used as a macroinitiator for atom transfer radical polymerization of acrylates.
2-Bromobutyryl bromide Acetyl bromide 2-Bromoisobutyrylchloride 2-bromobutyryl chloride 2-Bromoisobutyryl Bromide OXALYL BROMIDE Propionyl bromide Rocuronium bromide A-BROMOPROPIONYL BROMIDE 1-Bromopropionyl bromide 2-Bromopropionyl bromide Sodium bromate Ethidium bromide Allyl bromide Methyl bromide

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