Ammonium chloroplatinate

Ammonium chloroplatinate Basic information
Product Name:Ammonium chloroplatinate
Synonyms:Ammoniumchloroplatinate(IV);ammoniumplatinicchloride;diammonium,(oc-6-11)-platinate(2-hexachloro-;diammoniumhexachloroplatinate(2-);Platinate(2-),hexachloro-, aMMoniuM (1:2), (OC-6-11)-;Ammonium hexachloroplatinate(IV) 99.999% trace metals basis;Ammonium hexachloroplatinate(Ⅳ);platinicammoniumchloride
CAS:16919-58-7
MF:Cl6Pt.2H4N
MW:443.88
EINECS:240-973-0
Product Categories:chemical reaction,pharm,electronic,materials;halometallate salt;Inorganics
Mol File:16919-58-7.mol
Ammonium chloroplatinate Structure
Ammonium chloroplatinate Chemical Properties
Melting point °Cd ec.)
density 3.07 g/mL at 25 °C(lit.)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Powder
color Yellow
Specific Gravity3.065
Water Solubility Slightly soluble in water. Insoluble in alcohol, ether and concentrated hydrochloric acid.
Sensitive Hygroscopic
Merck 14,548
Exposure limitsACGIH: TWA 0.002 mg/m3
NIOSH: IDLH 4 mg/m3; TWA 0.002 mg/m3
Stability:hygroscopic
CAS DataBase Reference16919-58-7(CAS DataBase Reference)
EPA Substance Registry SystemAmmonium chloroplatinate (16919-58-7)
Safety Information
Hazard Codes T
Risk Statements 25-41-42/43
Safety Statements 22-26-36/37/39-45
RIDADR UN 3288 6.1/PG 3
WGK Germany 1
RTECS BP5425000
TSCA Yes
HazardClass 6.1
PackingGroup III
Hazardous Substances Data16919-58-7(Hazardous Substances Data)
ToxicityLD50 orl-rat: 195 mg/kg GTPZAB 21(7),55,77
MSDS Information
ProviderLanguage
Ammonium hexachloroplatinate(IV) English
SigmaAldrich English
ALFA English
Ammonium chloroplatinate Usage And Synthesis
Chemical PropertiesYELLOW CUBIC CRYSTALS
Chemical PropertiesAmmonium chloroplatinate is an orange-red crystalline cubic solid or yellow powder which decomposes when heated.
UsesPlatinum plating; manufacture of spongy platinum.
UsesElectroplating of platinum, manufacturing of platinum spongeAmmonium hexachloroplatinate(IV) is used in electroplating of platinum and to make spongy platinum. It reacts with copper(II) acetate and hydrogen sulfide to prepare Cu2PtIIPt3IVS8 which finds application in diamagnetic materials and semiconductors. It is also used in platinum plating. Further, it acts as an analytical reagent.
DefinitionChEBI: Ammonium hexachloroplatinate is an ammonium salt comprising separate ammonium cations and octahedral [PtCl6](2-) anions. It contains a hexachloroplatinate(2-).
Flammability and ExplosibilityNotclassified
Safety ProfilePoison by inhalation and ingestion. Human pulmonary system effects by inhalation. See also PLATINUM COMPOUNDS. An explosively unstable compound. Incompatible with KOH (boiling with alkali yields a product which, after drying, will explode @ 205' or if mixed with combustibles). When heated to decomposition it emits very toxic fumes of Cl-, NOx, and NH3.
Potential ExposureIt is used in photography, platinum plating and in the manufacture of platinum sponge.
ShippingUN3288 Toxic solids, inorganic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
IncompatibilitiesThis material is unstable and potentially explosive. Incompatible with strong oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.
Waste DisposalBecause of the high value of the metal, recovery is the economically indicated disposal method.
Ammonium chloroplatinate Preparation Products And Raw materials
Preparation ProductsPlatinum-->Chloroplantinic acid
Ammonium hexachloropalladate(IV) Ammonium hexachloroiridate(IV) Potassium chloroplatinate AMMONIUM TETRACHLOROPLATINATE(II) Chloroplantinic acid AMMONIUM Sodium chloroplatinate hexahydrate Platinum(II)-ammonium chloride CIS-TETRACHLORODIAMMINE PLATINUM (IV) TETRABUTYLAMMONIUM HEXACHLOROPLATINATE(IV) Ammonium chloroplatinate AMMONIUM AQUAPENTACHLORORHODATE(III) platinum trichloride trans-Dichlorodiamineplatinum(II) Trimethylbenzylammoniumhexachloroplatinate(IV), Premion, 99.99% (metals basis) Molybdic acid Ammonium carbonate 2-​[[(2-​ethylphenyl)​(2-​hydroxyethyl)​amino]​methyl]​-​3,​3-​difluoro-Propanenitrile

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