1,2-Dianilinoethane

1,2-Dianilinoethane Basic information
Product Name:1,2-Dianilinoethane
Synonyms:n,n’-diphenyl-ethylenediamin;N,N'-Difenylethylendiamin;N,N'-Diphenyl-1,2-ethylenediamine;N,N'-Diphenyl-alpha,omega-diaminoethane;NODX;Stabilite;sym-Diphenylethylenediamine;N,N-Diphenylethylenediamine~Wanzlicks
CAS:150-61-8
MF:C14H16N2
MW:212.29
EINECS:205-765-6
Product Categories:
Mol File:150-61-8.mol
1,2-Dianilinoethane Structure
1,2-Dianilinoethane Chemical Properties
Melting point 65-67 °C(lit.)
Boiling point 228°C 12mm
density 1.0799 (rough estimate)
refractive index 1.6000 (estimate)
Fp 228°C/12mm
form powder to crystal
pka4.67±0.50(Predicted)
color White to Light yellow to Light red
Water Solubility Sparingly soluble in water 0.072 g/L @ 25°C.
Merck 14,2990
BRN 646740
InChIInChI=1S/C14H16N2/c1-3-7-13(8-4-1)15-11-12-16-14-9-5-2-6-10-14/h1-10,15-16H,11-12H2
InChIKeyNOUUUQMKVOUUNR-UHFFFAOYSA-N
SMILESC(NC1=CC=CC=C1)CNC1=CC=CC=C1
CAS DataBase Reference150-61-8(CAS DataBase Reference)
EPA Substance Registry SystemN,N'-Diphenylethylenediamine (150-61-8)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
RTECS KV4800000
34
TSCA Yes
HS Code 29214200
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
1,2-Dianilinoethane Usage And Synthesis
Chemical PropertiesBEIGE TO LIGHT BROWN CRYSTALLINE POWDER
Uses1,2-Dianilinoethane can forms crystalline imidazolidines with aldehydes in the presence of AcOH. N-donating ligand. Can be used as a trapping agent for aldehydes.
ApplicationN,N′-Diphenylethylenediamine can be used:
To prepare nickel(II) chelates to study their chemical reactivities.
To prepare N-heterocyclic carbene (NHC) adducts by reacting with substituted benzaldehydes.
As a starting material to prepare substituted cyclic poly(methyl methacrylate)s.
Synthesis Reference(s)Synthetic Communications, 22, p. 1081, 1992 DOI: 10.1080/00397919208019300
Purification MethodsCrystallise the reagent from aqueous EtOH or MeOH. [Beilstein 12 H 543, 12 IV 986.]
1,2-Dianilinoethane Preparation Products And Raw materials
Preparation Products1,3,2-Diazaphospholidine, 2-chloro-1,3-diphenyl-
DI-O-TOLYLETHYLENEDIAMINE RARECHEM AL FB 0097 1,4-DIPHENYLPIPERAZINE BIS(1,3-DIPHENYL-2-IMIDAZOLIDINYLIDENE) AURORA 15227 N,N'-DI-P-TOLYLPIPERAZINE RARECHEM AL FB 0100 3'-(3,4-DICHLOROPHENYL)SPIRO-(2,3-DIHYDRO-1H-INDOLE-3,2'-THIAZOLIDINE)-2,4'-DIONE 2,2'-BISBENZOTHIAZOLINE RARECHEM AL FB 0099 3'-PHENYLSPIRO(2,3-DIHYDRO-1H-INDOLE-3,2'-THIAZOLIDINE)-2,4'-DIONE 1,2-Dianilinoethane RARECHEM AL FE 0050 1-(2,4-DICHLOROBENZY)-3'-(3,4-DICHLOROPHENYL)SPIRO(2,3-DIHYDRO-1H-INDOLE-3,2'-THIAZOLIDINE)-2,4'-DIONE 1,2-DIANILINOETHANE DIHYDROCHLORIDE 3-(4-ETHOXYPHENYL)SPIRO[1,3-THIAZOLIDINE-2,3'-INDOLINE]-4,7-DIONE N,N'-BIS(3-HYDROXYPHENYL)PIPERAZINE RARECHEM AL FB 0098

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