o-Toluoyl chloride

o-Toluoyl chloride Basic information

Product Name:	o-Toluoyl chloride
Synonyms:	Benzoyl chloride, 2-methyl-;o-Toluoyl chlori;o-Toluoyl chloride 99%;o-Toluoyl chloride, 2-(Chlorocarbonyl)toluene;o-Toluoyl chloride, 99% 5GR;2-methyl-benzoylchlorid;o-Toluic acid chloride;2-TOLUOYL CHLORIDE
CAS:	933-88-0
MF:	C8H7ClO
MW:	154.59
EINECS:	213-273-8
Product Categories:	ACIDHALIDE;Tolvaptan intermediate
Mol File:	933-88-0.mol

o-Toluoyl chloride Chemical Properties

Melting point	159.5-160.9 °C(Solv: ligroine (8032-32-4); dichloromethane (75-09-2))
Boiling point	88-90 °C/12 mmHg (lit.)
density	1.185 g/mL at 25 °C (lit.)
refractive index	n20/D 1.5549(lit.)
Fp	170 °F
storage temp.	Room Temperature, Under Inert Atmosphere
form	Liquid
Specific Gravity	1.185
color	Clear pale yellow to yellow to faintly pink
Water Solubility	Reacts with water.
Sensitive	Moisture Sensitive
BRN	507933
InChIKey	GPZXFICWCMCQPF-UHFFFAOYSA-N
CAS DataBase Reference	933-88-0(CAS DataBase Reference)
NIST Chemistry Reference	Benzoyl chloride, 2-methyl-(933-88-0)
EPA Substance Registry System	Benzoyl chloride, 2-methyl- (933-88-0)

Safety Information

Hazard Codes	C
Risk Statements	34-36/37
Safety Statements	23-26-27-36/37/39-45-24/25
RIDADR	UN 3265 8/PG 2
WGK Germany	3
F	10-19-21
Hazard Note	Corrosive/Moisture Sensitive
TSCA	Yes
HazardClass	8
PackingGroup	II
HS Code	29163900

MSDS Information

Provider	Language
2-Methylbenzoyl chloride	English
SigmaAldrich	English
ACROS	English
ALFA	English

o-Toluoyl chloride Usage And Synthesis

Chemical Properties	clear pale yellow to yellow to faintly pink liquid
Uses	O-Toluoyl Chloride is used in the synthesis if quinolinone compounds as SARS CoV 3CLpro inhibitors. Also used in the synthesis of benzooxaboroles as orally active anti-inflammatory agents.
General Description	Flash vacuum pyrolysis of o-toluoyl chloride at 780°C and 0.5 mmHg yields benzocyclobutenone.

o-Toluoyl chloride Preparation Products And Raw materials

Raw materials	Nitrogen-->o-Toluic acid-->4-Iodobenzoyl chloride-->2-Iodotoluene-->Terephthaloyl chloride
Preparation Products	Bensulfuron methyl-->2-METHYLBENZANILIDE-->Methyl 2-chloromethylbenzoate-->Mepronil-->2-METHYLBENZOYL CYANIDE-->1-[9-Ethyl-6-(2-methylbenzoyl)-9H-carbazol-3-yl]ethanone 1-(O-acetyloxime)-->O-TOLUAMIDE-->ETHYL-O-TOLYL KETONE-->2-METHYL-3-HEPTANONE-->o-Toluic hydrazide-->3-OXO-3-O-TOLYL-PROPIONIC ACID ETHYL ESTER-->2'-METHYLPHENACYL BROMIDE-->2-methyl-4-(2-methyl-benzoylamino)-benzoic acid

9-FLUORENONE-4-CARBONYL CHLORIDE BENZOYL CHLORIDE,2-(4-CHLOROBENZOYL)- 2,4,6-TRIISOPROPYLBENZOYL CHLORIDE 3-NITRO-P-TOLUOYL CHLORIDE 4-toluoyl chloride phenylhydrazone 6-NITRO-O-TOLUOYL CHLORIDE m-Toluoyl chloride, 4-ethoxy- (7CI) meta-toluoyl chloride,M-TOLUOYL CHLORIDE,3-Toluoyl chloride,Toluoyl chloride,3-METHYLBENZOYL CHLORIDE / M-TOLUOYL CHLORIDE,m-Toluoyl chloride(m-Toluicchloride) Benzoyl chloride, 2,5-dimethyl- (6CI,7CI,8CI,9CI) m-Toluoyl chloride, 4-propoxy- (7CI) 2-(BENZOYLOXYMETHYL)BENZOYL CHLORIDE alpha,alpha,alpha,4-Tetrafluoro-m-toluoyl chloride,à,à,à,4-tetrafluoro-m-toluoyl chloride à,à,à,5-tertafluoro-o-toluoyl chloride,alpha,alpha,alpha,5-Tertafluoro-o-toluoyl chloride Mepiquat chloride 2,3-Dimethylbenzene-1-carbonyl chloride 4-FLUORO-M-TOLUOYL CHLORIDE 5-Fluoro-o-toluoyl chloride 2-[[(2-ethylphenyl)(2-hydroxyethyl)amino]methyl]-3,3-difluoro-Propanenitrile

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