(Trifluoromethoxy)benzene

(Trifluoromethoxy)benzene Basic information

Product Name:	(Trifluoromethoxy)benzene
Synonyms:	PHENYL TRIFLUOROMETHYL ETHER;(Trifluormethoxy)-benzol;(TRIFLUOROMETHOXY)BENZENE;(trifluoromethoxy)-benzen;trifluoroanisole;α,α,α-Trifluoroanisole;1-(TRIFLUOROMETHOXY)BENZENE;Trifluoeomethoxybenzene
CAS:	456-55-3
MF:	C7H5F3O
MW:	162.11
EINECS:	207-269-5
Product Categories:	Aromatic Halides (substituted);Trifluoromethoxybenzene Series
Mol File:	456-55-3.mol

(Trifluoromethoxy)benzene Chemical Properties

Melting point	-49.9°C
Boiling point	102 °C(lit.)
density	1.226 g/mL at 25 °C(lit.)
vapor pressure	41.3 mm Hg ( 25 °C)
refractive index	n20/D 1.406(lit.)
Fp	54 °F
storage temp.	Sealed in dry,2-8°C
form	clear liquid
color	Colorless to Almost colorless
Specific Gravity	1.226
BRN	2043132
InChIKey	GQHWSLKNULCZGI-UHFFFAOYSA-N
CAS DataBase Reference	456-55-3(CAS DataBase Reference)
NIST Chemistry Reference	Trifluoromethoxybenzene(456-55-3)
EPA Substance Registry System	(Trifluoromethoxy)benzene (456-55-3)

Safety Information

Hazard Codes	F,Xi,C
Risk Statements	11-36/37/38
Safety Statements	16-26-36/37/39-9-33
RIDADR	UN 1993 3/PG 2
WGK Germany	3
Hazard Note	Flammable/Corrosive
TSCA	T
HazardClass	3
PackingGroup	II
HS Code	29093090

MSDS Information

Provider	Language
alpha,alpha,alpha-Trifluoroanisole	English
SigmaAldrich	English
ACROS	English
ALFA	English

(Trifluoromethoxy)benzene Usage And Synthesis

Chemical Properties	Colorless to light yellow liqui
Synthesis Reference(s)	The Journal of Organic Chemistry, 29, p. 1, 1964 DOI: 10.1021/jo01024a001
General Description	(Trifluoromethoxy)benzene is an aryl trifluoromethyl ether. (Trifluoromethoxy)benzene can be prepared from 4-chloro-1-(trifluoromethoxy)benzene via hydrogenolysis. Conformation of (trifluoromethoxy)benzene in the gas phase has been studied by electron diffraction and spectroscopy supplemented with ab initio calculations.

(Trifluoromethoxy)benzene Preparation Products And Raw materials

Raw materials	ROSOLIC ACID-->Phenol-->Carbon tetrachloride
Preparation Products	2-(TRIFLUOROMETHOXY)BENZAMIDE-->4'-(Trifluoromethoxy)acetophenone-->2-Trifluoromethoxyphenol-->4-(Trifluoromethoxy)nitrobenzene-->1-Bromo-4,5-difluoro-2-(trifluoromethoxy)benzene-->2-Methyl-1[4-(trifluoromethoxy)phenyl] propan-1-one-->2-(Trifluoromethoxy)chlorobenzene-->2-(Trifluormethoxy)phenylboronic acid

1-BROMO-4-METHOXY-2-TRIFLUOROMETHOXY-BENZENE 4-Methoxybenzyl cyanide 1,2-DICHLORO-3-TRIFLUOROMETHOXY-BENZENE 2,3-Dihydro-2,2-dimethyl-7-benzofuranol 1-CHLORO-3-FLUORO-4-(TRIFLUOROMETHOXY)BENZENE 1-bromo-3-(3-chloropropyl)-5-(trifluoromethoxy)benzene 1-isothiocyanato-2-(trifluoromethoxy)benzene 4-Fluoro-3-nitro(trifluoromethoxy)benzene m-Anisyl alcohol 4-(TRIFLUOROMETHOXY)BENZOYL FLUORIDE 3-(METHOXYMETHOXY)BENZALDEHYDE 3-(trifluoromethoxy)benzoyl fluoride 1-isothiocyanato-4-(trifluoromethoxy)benzene 1-(2-bromoethyl)-3-(trifluoromethoxy)benzene 1-(3-chloropropyl)-4-methoxy-2-(trifluoromethoxy)benzene 2-bromo-4-chloro-1-(trifluoromethoxy)benzene 2-bromo-4-fluoro-1-(trifluoromethoxy)benzene 1-bromo-3,5-difluoro-2-(trifluoromethoxy)benzene

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