Cellulose acetate

Cellulose acetate Basic information
Product Name:Cellulose acetate
Synonyms:360E16;A 50T;AC 300;AC 311075;AC 3533B;AC 398-10;AC 61;Aceplast LS
CAS:9004-35-7
MF:[C6H7O2(OH)3-m(OOCCH3)m],m=0~3
MW:0
EINECS:246-466-0
Product Categories:Cellulose;Materials Science;Natural Polymers;Polymer Science;Polymers
Mol File:Mol File
Cellulose acetate Structure
Cellulose acetate Chemical Properties
Melting point 230-300℃
Boiling point 210 °C
density 1.3 g/mL at 25 °C (lit.)
refractive index n20/D 1.475(lit.)
storage temp. 2-8°C
solubility The solubility of cellulose acetate is greatly influenced by the level of acetyl groups present. In general, cellulose acetates are soluble in acetone–water blends of varying ratios, dichloromethane– ethanol blends, dimethyl formamide, and dioxane.
form Powder
Specific Gravity1.3
color White
Odorat 100.00?%. odorless
Merck 13,1978
Stability:Stable. Combustible. Incompatible with strong oxidizing agents.
EPA Substance Registry SystemCellulose acetate (9004-35-7)
Safety Information
WGK Germany -
HS Code 39121100
Hazardous Substances Data9004-35-7(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Cellulose acetate Usage And Synthesis
Chemical PropertiesCellulose acetate, white powder, is the general name for the acetic acid esters of cellulose, cellulose pentaacetate, C6H5(OOCCH3)5, cellulose tetraacetate, C6H6(OOCCH3)4 and cellulose triacetate,C6H7O2(OOCCH3)3. Cellulose acetate occurs as a hygroscopic white to off-white, freeflowing powder, pellet, or flake. It is tasteless and odorless, or may have a slight odor of acetic acid.Cellulose acetate is a tough, flexible, slow-burning and long-lasting material used in the production of plastic film for food packaging,magnetic tape, and movie film.
UsesCA can be used as a material in packaging, clothing and pharmaceuticals industries. It can also be used in the formation of polymeric electrolyte for the fabrication of electrochemical devices like fuel cells, solar cells and supercapacitors.
UsesCellulose acetate was used in the fabrication of gold microelectrode for electrochemical monochloramine measurement. Cellulose acetate based membranes are used in the separations in aqueous systems and in reverse osmosis process. It has been reported to be used to desalinate seawater.Cellulose acetate was used for biosensor encapsulation. It was used in the preparation of cellulose acetate nanofibre felt structure, cellulose acetate fibers.
DefinitionChEBI: Cellulose acetate is a glucan derivative obtained through the esterification of cellulose by acetic anhydride or acetic acid, resulting in the substitution of some of the hydroxy groups of cellulose by acetyl groups. It is used in a variety of applications including base material for photographic film, clothing, membrane filters, coatings, food packaging, and as a frame material for eyeglasses. It is a glucan derivative and an acetate ester.
Production MethodsCellulose acetate is prepared from highly purified cellulose by treatment with acid catalysis and acetic anhydride.
General DescriptionCellulose acetate (CA) is a class of cellulose based esters which can be produced by a reaction of cellulose with acetic acid and acetic anhydride. It can be used in a variety of forms such as films, membranes, and fibers. It can be used as a biodegradable polymer in medical and automotive applications.
Agricultural UsesCellulose acetate is an ester in which cellulose (cotton linters or wood pulp) is treated with a mixture of acetic anhydride, acetic acid and concentrated sulphuric acid. This solution, when treated with water, forms a flocculent white mass of cellulose acetate which is used as a fiber and in lacquers, non-breakable glass and varnishes.
Industrial usesCellulose acetate is an amber-colored, transparentmaterial made by the reaction of celluloseand acetic acid or acetic anhydride in the presenceof sulfuric acid.
It is thermoplastic and easily molded. Themolded parts or sheets are tough, easilymachined, and resistant to oils and many chemicals.In coatings and lacquers the material isadhesive, tough, and resilient, and does not discoloreasily. Cellulose acetate fiber for rayonscan be made in fine filaments that are strongand flexible, nonflammable, mildew proof, andeasily dyed. Standard cellulose acetate formolding is marketed in flake form.
In practical use, cellulose acetate moldingsexhibit toughness superior to most other general-purpose plastics. Flame-resistant formulationsare currently specified for small appliancehousings and for other uses requiring this property.Uses for cellulose acetate molding materialsinclude toys, buttons, knobs, and otherparts where the combination of toughness andclear transparency is a requirement.

SafetyCellulose acetate is widely used in oral pharmaceutical products and is generally regarded as a nontoxic and nonirritant material.
storageCellulose acetate is stable if stored in a well-closed container in a cool, dry place. Cellulose acetate hydrolyzes slowly under prolonged adverse conditions such as high temperature and humidity, with a resultant increase in free acid content and odor of acetic acid.
IncompatibilitiesCellulose acetate is incompatible with strongly acidic or alkaline substances. Cellulose acetate is compatible with the following plasticizers: diethyl phthalate, polyethylene glycol, triacetin, and triethyl citrate.
Regulatory StatusIncluded in the FDA Inactive Ingredients Database (oral tablets). Included in the Canadian List of Acceptable Non-medicinal Ingredients.
Cellulose acetate Preparation Products And Raw materials
Raw materialsAcetic anhydride
Cellulose acetate textile fibers CELLULOSE TRIACETATE CELLULOSE ACETATE TRIMELLITATE,CELLULOSE ACETATE SAC 20,CELLULOSE ACETATE (ACRYLAMIDOMETHYL)CELLULOSE ACETATE PROPIONATE Whatman(R) syringe filter units, disposable, cellulose acetate CELLULOSE ACETATE STEARATE CELLULOSE ACETATE BUTYRATE cellulore Cellulose Acetate Plastics cellulose acetate esterase CELLULOSE ACETATE, ERGOTAMINE TARTRATE& CAFFEINE ANHYDROUS Blotting-Cellulose acetate membranes,Cellulose acetate membranes CELLULOSE ACETATE PROPIONATE CARBOXYLATE Cellulose acetate cigarette filter tow,Cellulose acetate staple fiber Includes cellulose acetate butyrate and cellulose triacetate resins Cellulose, acetate butanoate, carboxymethyl ether CELLULOSE ACETATE PROPIONATE Cellulose acetate phthalate

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