ChemicalBook Product Catalog Chemical Reagents Organic reagents Tosylate 2,2,2-Trifluoroethyl trifluoromethanesulfonate

2,2,2-Trifluoroethyl trifluoromethanesulfonate

2,2,2-Trifluoroethyl trifluoromethanesulfonate Basic information
Product Name:2,2,2-Trifluoroethyl trifluoromethanesulfonate
Synonyms:2,2,2-trifluoroethyltrifluorometanesulfonicacid;methanesulfonicacid,trifluoro-,2,2,2-trifluoroethylester;TRIFLUOROMETHANESULFONIC ACID 2,2,2-TRIFLUOROETHYL ESTER;TFOL-TF;2,2,2-TRIFLUOROETHYL TRIFLATE;2,2,2-TRIFLUOROETHYL TRIFLUOROMETHANESULFONATE;2,2,2-TRIFLUOROETHYL TRIFLUOROMETHANESULPHONATE;2,2,2-Trifluoroethyltrifluoromethanesulphonate97%
CAS:6226-25-1
MF:C3H2F6O3S
MW:232.1
EINECS:458-390-7
Product Categories:Intermediates & Fine Chemicals;Pharmaceuticals;Fluorinated Building Blocks;Fluorinating Reagents & Building Blocks for Fluorinated Biochemical Compounds;Synthetic Organic Chemistry;Sulfur & Selenium Compounds
Mol File:6226-25-1.mol
2,2,2-Trifluoroethyl trifluoromethanesulfonate Structure
2,2,2-Trifluoroethyl trifluoromethanesulfonate Chemical Properties
Boiling point 89-91°C
density 1,61 g/cm3
refractive index 1.3037
RTECS PB2775000
Fp >110°(230°F)
storage temp. 2-8°C
solubility Chloroform, Methanol (Slightly)
form Liquid
color Colorless to yellow
Water Solubility Slightly soluble in water.
Sensitive Moisture Sensitive
InChIKeyRTMMSCJWQYWMNK-UHFFFAOYSA-N
CAS DataBase Reference6226-25-1(CAS DataBase Reference)
EPA Substance Registry SystemMethanesulfonic acid, trifluoro-, 2,2,2-trifluoroethyl ester (6226-25-1)
Safety Information
Hazard Codes Xi,T,C
Risk Statements 36/37/38-34-23/25
Safety Statements 26-36/37/39-45
RIDADR 3265
WGK Germany 3
Hazard Note Irritant
HazardClass TOXIC, CORROSIVE
HazardClass 8
PackingGroup Ⅱ
HS Code 29055900
MSDS Information
2,2,2-Trifluoroethyl trifluoromethanesulfonate Usage And Synthesis
UsesA fluorine-containing alkyl alkanesulfonate with cyctotoxity towards cultured leukemia L1210 cells.
Uses2,2,2-Trifluoroethyl trifluoromethanesulfonate is a powerful trifluoroethylating agent which is useful for synthesis of fluorinated amino acids. It is used as a reagent in thenantioselective preparation of cyclic N-aryl hydroxamic acids via phase-transfer catalyzed alkylation of nitrobenzyl bromides to give nirophenylalanines.
UsesReagent used in thenantioselective preparation of cyclic N-aryl hydroxamic acids via phase-transfer catalyzed alkylation of nitrobenzyl bromides to give nirophenylalanines
2,2,2-Trifluoroethyl trifluoromethanesulfonate Preparation Products And Raw materials
Preparation Products2,2,2-Trifluoroethanol-->2,2,3,3,3-Pentafluoropropyl 2,2,2-trifluoroethyl carbonate-->4-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)-1-(2,2,2-trifluoroethyl)-1H-pyrazole-->TFEC-->tert-butyl (1-(2,2,2-trifluoroethyl)piperidin-4-yl)carbaMate-->4-NITRO-1-(2,2,2-TRIFLUOROETHYL)-1H-PYRAZOLE-->ethyl 1-(2,2,2-trifluoroethyl)piperidine-4-carboxylate-->3-Methyl-5-(2,2,2-trifluoroethoxy)picolinonitrile-->2H-1-BENZAZEPIN-2-ONE 6-FLUORO-1,3,4,5-TETRAHYDRO-3-[4-[3-METHOXY-4-(4-METHYL-1H-IMIDAZOL-1-YL)PHENYL]-1H-1,2,3-TRIAZOL-1-YL]-1-(2,2,2-TRIFLUOROETHYL)--->(5-(2,2,2-trifluoroethoxy)pyridin-2-yl)methanol-->5-BROMO-2-(2,2,2-TRIFLUORO-ETHOXY)-PYRIMIDINE
BUPIRIMATE DIBUTYLBORON TRIFLUOROMETHANESULFONATE Ethyl methanesulfonate Ethyl trifluoromethanesulfonate 2,2-DIFLUOROETHYL TRIFLUOROMETHANESULFONATE Levofloxacin Methylate 2,2,2-Trifluoroethyl trifluoromethanesulfonate Trifluoromethanesulfonic anhydride Pefloxacin mesylate Sodium trifluoromethanesulfonate 2,2,2-TRIFLUOROETHYL METHANESULFONATE YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE TRIFLUOROACETYL TRIFLATE FLUOROSULFONIC ACID COPPER(II) TRIFLUOROMETHANESULFONATE Sodium isethionate Lithium triflate HEXAFLUOROISOPROPYL TRIFLUOROMETHANESULFONATE
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