2-(6-BROMOHEXYLOXY)TETRAHYDRO-2H-PYRAN

2-(6-BROMOHEXYLOXY)TETRAHYDRO-2H-PYRAN Basic information
Product Name:2-(6-BROMOHEXYLOXY)TETRAHYDRO-2H-PYRAN
Synonyms:2-[(6-bromohexyl)oxy]tetrahydro-2h-pyra;1-Bromo-6-tetrahydropyranyloxyhexane, 6-Tetrahydropyraryloxy-1-bromohexane;2H-Pyran, 2-((6-bromohexyl)oxy)tetrahydro-;Einecs 258-891-9;AURORA KA-3062;2-(6-BROMOHEXYLOXY)TETRAHYDRO-2H-PYRAN;2-(6-BROMOHEXYLOXY)TETRAHYDROPYRAN;1-BROMO-6-TETRAHYDROPYRANYLOXYHEXANE
CAS:53963-10-3
MF:C11H21BrO2
MW:265.19
EINECS:258-891-9
Product Categories:
Mol File:53963-10-3.mol
2-(6-BROMOHEXYLOXY)TETRAHYDRO-2H-PYRAN Structure
2-(6-BROMOHEXYLOXY)TETRAHYDRO-2H-PYRAN Chemical Properties
Melting point 90-91℃
Boiling point 125 °C0.1 mm Hg(lit.)
density 1.209 g/mL at 25 °C(lit.)
refractive index n20/D 1.478(lit.)
Fp >230 °F
storage temp. 2-8°C
solubility Chloroform, Dichloromethane, Dimethyl Sulfoxide, Ethyl Acetate
form Oil
color Light Yellow
EPA Substance Registry System2H-Pyran, 2-[(6-bromohexyl)oxy]tetrahydro- (53963-10-3)
Safety Information
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
2-(6-BROMOHEXYLOXY)TETRAHYDRO-2H-PYRAN Usage And Synthesis
Uses2-(6-Bromohexyloxy)tetrahydro-2H-pyran is an intermediate in the synthesis of (4E, 11Z)-Sphingadienine-C18-1-phosphate which is a sphingoid base of sea cucumber cerebroside that may have cytotoxicity activity against human colon cancer cells.
Uses2-(6-Bromohexyloxy)tetrahydro-2H-pyran may be used as a reactant in the synthesis of diethyl 6-(tetrahydropyran-2-yloxy)hexylphosphonate and 13-(tetrahydo-2H-pyran-2-yloxy)-6-tridecyn-1-ol.
General Description2-(6-Bromohexyloxy)tetrahydro-2H-pyran can be synthesized by reacting 6-bromohexanol and pyridinium p-toluenesulfonate in anhydrous dichloromethane.
2-(6-BROMOHEXYLOXY)TETRAHYDRO-2H-PYRAN Preparation Products And Raw materials
Preparation Productstrans-cis-7,11-hexadecadienylacetate-->Tetratriaconta-16(Z),19(Z),22(Z),25(Z),28(Z),31(Z)-hexaenoic Acid
1-Bromohexane 2-(6-BROMOHEXYLOXY)TETRAHYDRO-2H-PYRAN 6-Bromo-1-hexanol

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