P-TOLYLUREA

P-TOLYLUREA Basic information
Product Name:P-TOLYLUREA
Synonyms:P-TOLYLUREA;p-Tolylurea,99%;4-METHYLPHENYLUREA;AKOS B028828;1-(p-Methylphenyl)urea;1-(p-Tolyl)urea;p-Tolylcarbamide;p-Methylphenylurea
CAS:622-51-5
MF:C8H10N2O
MW:150.18
EINECS:210-739-2
Product Categories:
Mol File:622-51-5.mol
P-TOLYLUREA Structure
P-TOLYLUREA Chemical Properties
Melting point 178-181 °C
Boiling point 255℃
density 1.192
refractive index 1.6180 (estimate)
Fp 108℃
storage temp. 2-8°C
pka14.61±0.50(Predicted)
form powder to crystal
color White to Almost white
Water Solubility 3.07g/L(45 ºC)
BRN 2208088
CAS DataBase Reference622-51-5(CAS DataBase Reference)
EPA Substance Registry Systemp-Tolylurea (622-51-5)
Safety Information
Risk Statements 33
Safety Statements 24/25
RTECS YU4200000
HazardClass IRRITANT
HS Code 29242100
MSDS Information
ProviderLanguage
ACROS English
ALFA English
P-TOLYLUREA Usage And Synthesis
Chemical Propertiesbeige crystalline powder
General DescriptionColorless crystals.
Air & Water ReactionsSlightly soluble in hot water.
Reactivity ProfileP-TOLYLUREA is an amide. Amides/imides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides/imides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx).
Health HazardACUTE/CHRONIC HAZARDS: Slightly toxic. Hazardous decomposition products.
Purification MethodsCrystallise the urea from H2O (m 186o), EtOH/water (1:1) or aqueous AcOH (m 184o). [Beilstein 12 H 941, 12 I 425, 12 II 512, 12 III 2084, 12 IV 1923.]
P-TOLYLUREA Preparation Products And Raw materials
Preparation Products1-(4-METHYLPHENYL)PYRIMIDINE-2,4,6(1H,3H,5H)-TRIONE
N-(3,4-DIMETHYLPHENYL)UREA AURORA 11831 AURORA 19947 AURORA 19945 (2,4,6-trimethylphenyl)urea 1-(3-CHLORO-4-METHYLPHENYL)UREA 5-FLUORO-O-TOLYLUREA 3,3'-(4-METHYL-1,3-PHENYLENE) BIS (1,1-DIMETHYLUREA) AURORA 19950 P-TOLYLUREA 2,4-DIMETHYLPHENYLUREA (+)-1-[(R)-α-Methylbenzyl]-3-p-tolylurea,1-[(R)-α-Methylbenzyl]-3-p-tolylurea 1,3-di-p-tolylurea (+)-1-[(R)-α-Methylbenzyl]-3-o-tolylurea 4-UREIDO-BENZOIC ACID 4-[(ANILINOCARBONYL)AMINO]BENZOIC ACID N-(4-ethylphenyl)urea Chlorotoluron

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