(+)-(18-CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID

(+)-(18-CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID Basic information
Product Name:(+)-(18-CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID
Synonyms:(+)-(18-CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID;(2R,3R,11R,12R)-1,4,7,10,13,16-HEXAOXACYCLOOCTADECANE-2,3,11,12-TETRACARBOXYLIC ACID;(+)-(CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID;C90001;(+)-(18-Crown-6)-2,3,11,12-tetracarboxylic acid,(2R,3R,11R,12R)-1,4,7,10,13,16-Hexaoxacyclooctadecane-2,3,11,12-tetracarboxylic acid;(+)-18-Crown-6 tetracarboxylic Acid;Bis(L-tartaric Acid) 18-Crown-6;(+)-(18-Crown-6)-2,3,11,12-tetracarboxylic acid 97%
CAS:61696-54-6
MF:C16H24O14
MW:440.35
EINECS:
Product Categories:Chelating Agents, Ligands;Chelating Agents & Ligands
Mol File:61696-54-6.mol
(+)-(18-CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID Structure
(+)-(18-CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID Chemical Properties
Melting point 210-212 °C (lit.)
Boiling point 798.9±60.0 °C(Predicted)
density 1.399±0.06 g/cm3(Predicted)
storage temp. -20°C Freezer, Under Inert Atmosphere
solubility Methanol (Slightly), Water (Slightly)
form Solid
pka1.95±0.70(Predicted)
color Off-White to Pale Yellow
optical activity[α]20/D +62°, c = 1 in methanol
BRN 4240375
Stability:Hygroscopic
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 2932990090
MSDS Information
ProviderLanguage
SigmaAldrich English
(+)-(18-CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID Usage And Synthesis
Chemical Properties(+)-(18-CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID is White Solid
UsesDerived tetracarboxylic acid chloride of this crown ether reacts with meta- and para-xylylene diamines to form chiral captands in high yields. Used as a chiral selector in capillary zone electrophoresis for the separation of a variety of optically active amines. Synthesis of monoamides.
Uses(+)-(18-CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID is a calcium and barium chelator. A useful chiral NMR discriminating agent for underivatized amino acids
(+)-(18-CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID Preparation Products And Raw materials
ISOPROPYL TRIGLYCOL PENTAETHYLENE GLYCOL MONOMETHYL ETHER HEXAETHYLENE GLYCOL MONOMETHYL ETHER 2-[2-(2-METHOXYETHOXY)ETHOXY]ACETIC ACID 2-(2-Methoxyethoxy)acetic acid 18-Crown-6 (+)-(18-CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID PENTAETHYLENE GLYCOL Tetraethylene glycol dimethyl ether 3,6,9,12-tetraoxatetradecan-1-ol 3,6,9,12,15-pentaoxaheptadecane Bis[2-(2-hydroxyethoxy)ethyl] ether DL-GLYCERALDEHYDE DIMER (R)-(+)-2-METHOXYPROPIONIC ACID 1,4,7,10,13,16-HEXAOXACYCLOOCTADECANE-2-METHANOL HEPTAETHYLENE GLYCOL 3,6,9-TRIOXAUNDECANEDIOIC ACID D(+)-Malic acid

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