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| | ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Basic information | | Reactions |
| Product Name: | ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) | | Synonyms: | (1,5-Cyclooctadiene)rhodium(I) 2,4-pentanedionate;(1,5-cyclooctadiene)(2,4-pentanedionato)rhodium(I);Acetylacetonato(1,5-cyclooctadiene)rhodium(I),97%;Acetylacetonato(1,5-;(Acetylacetonato)(1,5-cyclooctadiene)rhodium(Ⅰ);NSC 240030;RHODIUM (1,5-CYCLOOCTADIENE)-2,4-PENTANEDIONATE;((1,2,5,6-eta)-1,5-cyclooctadiene)(2,4-pentanedionato-o,o’)-rhodiu | | CAS: | 12245-39-5 | | MF: | C13H19O2Rh | | MW: | 310.19 | | EINECS: | | | Product Categories: | organometallic complex;Rh | | Mol File: | 12245-39-5.mol |  |
| | ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Chemical Properties |
| Melting point | 138-140 °C(lit.) | | storage temp. | Inert atmosphere,2-8°C | | form | Crystals | | color | Yellow to orange | | Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents | | Sensitive | Air Sensitive | | Exposure limits | ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 | | InChIKey | WDIAJTWVVLHUJU-SUESZSCISA-N |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-37/39 | | WGK Germany | 3 | | RTECS | VI9292000 | | TSCA | No | | HS Code | 28439000 |
| | ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Usage And Synthesis |
| Reactions |
- Precursor for asymmetric hydrogenation reactions.
- Rh-catalyzed carbozincation of ynamides.
| | Chemical Properties | Orange crystal | | Uses | Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis | | General Description | Atomic number of base material: 45 Rhodium | | Safety Profile | Poison by
intraperitoneal route. When heated to
decomposition it emits toxic fumes of Rh |
| | ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Preparation Products And Raw materials |
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