ENDOSULFAN SULFATE

ENDOSULFAN SULFATE Basic information
Product Name:ENDOSULFAN SULFATE
Synonyms:THIODAN SULFATE;BENZOEPIN SULFATE;ENDOSULFAN SULFATE;ENDOSULFAN-SULPHATE;6,7,8,9,10,10-HEXACHLORO-1,5,5A,6,9,9A-HEXAHYDRO-6,9-METHANO-2,3,4-BENZODIOXYTHIEPIN-3,3-DIOXIDE;6,7,8,9,10,10-HEXACHLORO-1,5,5A,6,9,9A-HEXAHYDRO-6,9-METHANO-2,4,3-BENZODIOXATHIEPIN-3,3-DIOXIDE;3-dimethanol,1,4,5,6,7,7-hexachloro-5-norbornene-cyclicsulfate;5-Norbornene-2,3-dimethanol, 1,4,5,6,7,7-hexachloro-, cyclic sulfate
CAS:1031-07-8
MF:C9H6Cl6O4S
MW:422.92
EINECS:623-765-8
Product Categories:CyclodienesAlphabetic;EA - EO;AcaricidesPesticides;Alpha sort;CyclodienesPesticides&Metabolites;E;EA - EOEnvironmental Standards;E-GAlphabetic;Insecticides;Metabolites;Pesticides;Pesticides&Metabolites
Mol File:1031-07-8.mol
ENDOSULFAN SULFATE Structure
ENDOSULFAN SULFATE Chemical Properties
Melting point 147.71°C
Boiling point 480.7±45.0 °C(Predicted)
density 1.6835 (estimate)
vapor pressure 9.75 x 10-6 mmHg at 25 °C (subcooled liquid vapor pressure calculated from GC retention time data,Hinckley et al., 1990)
Fp -26 °C
storage temp. APPROX 4°C
solubility DMSO: Slightly Soluble,Methanol: Slightly Soluble
form Liquid
color Clear colorless
Water Solubility 117 ppb (Ali, 1978)
Henry's Law Constant4.64(x 10-5 atm?m3/mol) at 25 °C (approximate - calculated from water solubility and vapor pressure)
EPA Substance Registry SystemEndosulfan sulfate (1031-07-8)
Safety Information
Hazard Codes T+,N,Xn,F,T
Risk Statements 28-50/53-67-65-62-51/53-48/20-38-11-39/23/24/25-23/24/25
Safety Statements 22-24/25-45-60-61-62-36/37-16-7-33-29-9
RIDADR 2761
WGK Germany 3
RTECS RB9150000
HazardClass 6.1(a)
PackingGroup II
Hazardous Substances Data1031-07-8(Hazardous Substances Data)
MSDS Information
ENDOSULFAN SULFATE Usage And Synthesis
UsesEndosulfan Sulfate is a pesticide used in the control and protection of plant and vegetation.
General DescriptionWater solubility - <1 mg/L at 72°F.
Air & Water ReactionsInsoluble in water.
Reactivity ProfileENDOSULFAN SULFATE is an organochlorine and cyclodiene. ENDOSULFAN SULFATE is also a sulfite ester. Corrosive to iron. Hydrolyzed by aqueous alkali or acid, generating sulfur dioxide. Incompatible with strong oxidizing and reducing agents. Also incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. As an ester, ENDOSULFAN SULFATE will hydrolyze to form sulfur dioxide and diol; reaction is more rapid under basic conditions.
Health HazardHighly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire HazardNon-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Containers may explode when heated. Runoff may pollute waterways.
Environmental FateSoil. A mixed culture of soil microorganisms biodegraded endosulfan sulfate to endosulfan ether, endosulfan-a-hydroxy ether and endosulfan lactone (Verschueren, 1983). Indigenous microorganisms obtained from a sandy loam degraded endosulfan sulfate (a metabolite of a- and b-endosulfan) to endosulfan diol. This diol was converted to endosulfan a-hydroxy ether and trace amounts of endosulfan ether and both were degraded to endosulfan lactone (Miles and Moy, 1979). Using settled domestic wastewater inoculum, endosulfan sulfate (5 and 10 mg/L) did not degrade after 28 days of incubation at 25°C (Tabak et al., 1981).
Plant. In tobacco leaves, endosulfan sulfate was converted to a-endosulfan which subsequently hydrolyzed into endosulfandiol (Chopra and Mahfouz, 1977).
ENDOSULFAN SULFATE Preparation Products And Raw materials
Thiosulfan ENDOSULFAN ALCOHOL 2,3-Dichloropropene DI-N-PROPYL SULFITE DI-N-BUTYL SULFATE 6-Chlorohexanol 1,1-DICHLOROCYCLOPENTANE Diethyl sulfite ENDOSULFAN SULFATE 3,4-DICHLORO-1-BUTENE 1,6-Dichlorohexane trans-1,3-Dichloropropene 3-Chloro-1-butene Cyclopentyl chloride 2-ETHYLHEXYSULPHATE 1,3-DICHLORO-2-BUTENE Diethyl sulfate Dimethyl sulfate

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