ChemicalBook Product Catalog Organic Chemistry Hydrocarbons and derivatives Hydrocarbon nitrification 2-Bromo-4'-nitroacetophenone

2-Bromo-4'-nitroacetophenone

2-Bromo-4'-nitroacetophenone Basic information
Product Name:2-Bromo-4'-nitroacetophenone
Synonyms:ASISCHEM D48949;4'-NITROPHENACYL BROMIDE;4-NITROPHENACYL BROMIDE;AKOS BBS-00003952;ALPHA-BROMO-P-NITROACETOPHENONE;ALPHA-BROMO-4-NITROACETOPHENONE;A-BROMO-P-NITROACETOPHENONE;2-BROMO-4'-NITROACENTOPHENONE
CAS:99-81-0
MF:C8H6BrNO3
MW:244.04
EINECS:202-789-9
Product Categories:B;Bioactive Small Molecules;Aromatic Halides (substituted);Building Blocks;C7 to C8;Carbonyl Compounds;Cell Biology;Chemical Synthesis;Ketones;Organic Building Blocks
Mol File:99-81-0.mol
2-Bromo-4'-nitroacetophenone Structure
2-Bromo-4'-nitroacetophenone Chemical Properties
Melting point 94-99 °C(lit.)
Boiling point 325.2±17.0 °C(Predicted)
density 1.8033 (rough estimate)
refractive index 1.6090 (estimate)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Crystalline Powder
color Yellow to orange
BRN 393567
CAS DataBase Reference99-81-0(CAS DataBase Reference)
NIST Chemistry Referencep-Nitrophenacyl bromide(99-81-0)
EPA Substance Registry System2-Bromo-4'-nitroacetophenone (99-81-0)
Safety Information
Hazard Codes C,Xi
Risk Statements 34-37
Safety Statements 26-36/37/39-45
RIDADR UN 3261 8/PG 2
WGK Germany 3
F 19
Hazard Note Irritant
TSCA Yes
HazardClass 8
PackingGroup III
HS Code 29147000
MSDS Information
ProviderLanguage
2-Bromo-4'-nitroacetophenone English
SigmaAldrich English
ACROS English
ALFA English
2-Bromo-4'-nitroacetophenone Usage And Synthesis
Chemical Propertiesyellow to orange crystalline powder
Uses2-Bromo-4′-nitroacetophenone was used to study the pKa of the histidine-34 imidazole.
Synthesis Reference(s)Synthesis, p. 487, 1980 DOI: 10.1055/s-1980-29067
Purification MethodsCrystallise it from *C6H6/pet ether. [Beilstein 7 IV 661.]
2-Bromo-4'-nitroacetophenone Preparation Products And Raw materials
Preparation ProductsFGH-10019-->1H-Pyrrole-3-carboxylic acid, 2-aMino-5-(4-nitrophenyl)-, ethyl ester-->2-(CHLOROMETHYL)-4-(4-NITROPHENYL)-1,3-THIAZOLE-->4-imidazo[2,1-b][1,3]thiazol-6-ylaniline
ACETOPHENONE-D8 4'-Bromoacetophenone 3-Bromoanisole 3-Nitroacetophenone 4-Nitroacetophenone p-Nitrophenylacetonitrile -Bromo-2'-Nitroacetophenone,2-BROMO-2'-NITROACETOPHENONE Clidinium bromide Sodium bromate 2',4'-Dichloroacetophenone 2-Bromoacetophenone 3-Bromonitrobenzene Bromonitromethane Ethidium bromide Bromine Methyl bromide 2-Nitroacetophenone PIPERACETAZINE (250 MG)
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