(S)-(-)-1-BENZYL-2-PYRROLIDINEMETHANOL

(S)-(-)-1-BENZYL-2-PYRROLIDINEMETHANOL Basic information
Product Name:(S)-(-)-1-BENZYL-2-PYRROLIDINEMETHANOL
Synonyms:(1-Benzyl-2-pyrrolidinyl)methanol;[1-(phenylmethyl)-2-pyrrolidinyl]methanol;[1-(phenylmethyl)pyrrolidin-2-yl]methanol;1-N-Benzyl-L-prolinol;(S)-1-(Phenylmethyl)-2-pyrrolidinemethanol;N-BENZYL-L-PROLINOL;(S)-(1-BENZYL-PYRROLIDIN-2-YL)-METHANOL;S(-)-1-BENZYLPYRROLIDINE-2-METHANOL
CAS:53912-80-4
MF:C12H17NO
MW:191.27
EINECS:
Product Categories:
Mol File:53912-80-4.mol
(S)-(-)-1-BENZYL-2-PYRROLIDINEMETHANOL Structure
(S)-(-)-1-BENZYL-2-PYRROLIDINEMETHANOL Chemical Properties
Boiling point 115-120 °C/0.5 mmHg (lit.)
density 1.08 g/mL at 25 °C (lit.)
refractive index n20/D 1.541(lit.)
Fp >230 °F
storage temp. Inert atmosphere,2-8°C
pka14.77±0.10(Predicted)
optical activity[α]20/D 72.7°, neat
BRN 3663640
InChIKeyZAIQBJPTOXDDKA-UHFFFAOYSA-N
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
3-10-34
HazardClass IRRITANT
HS Code 2933998090
MSDS Information
ProviderLanguage
SigmaAldrich English
(S)-(-)-1-BENZYL-2-PYRROLIDINEMETHANOL Usage And Synthesis
Chemical PropertiesColorless to pale yellow liquid
UsesPrecursor in the synthesis of proline-derived homochiral amine oxides. Starting material for enantiomerically pure 3-hydroxypiperidine, a structural feature present in many natural products.
(S)-(-)-1-BENZYL-2-PYRROLIDINEMETHANOL Preparation Products And Raw materials
Preparation Products(S)-3-Amino-1-N-Boc-piperidine
2-[(2-BENZYL-7-BROMO-2-AZABICYCLO[2.2.1]HEPT-6-YL)OXY]-5-BROMOBENZALDEHYDE Trityl-L-Proline 2-BENZYL-7-BROMO-6-ISOPROPOXY-2-AZABICYCLO[2.2.1]HEPTANE N-BENZYL-L-PROLINE ETHYL ESTER (+)-(3R,7aS)-Tetrahydro-3-phenyl-3H,5H-pyrrolo1,2-coxaole-5-one (S)-(-)-1-BENZYL-2-PYRROLIDINEMETHANOL L-Proline, 1-benzoyl-4-[[(9H-fluoren-9-ylmethoxy)carbonyl]amino]-, (4S)- (9CI) (S)-(-)-1-(2-METHOXYBENZOYL)-2-(METHOXYMETHYL)PYRROLIDINE 2-CLTRT RESIN-PRO-OBT (S)-1-BENZYL-5-HYDROXYMETHYL-2-PYRROLIDINONE N1-(4-[(2-BENZYL-7-BROMO-2-AZABICYCLO[2.2.1]HEPT-6-YL)OXY]PHENYL)ACETAMIDE abbeymycin tomaymycin chicamycin A (S)-1-BENZYL-5-CARBOXY-2-PYRROLIDINONE TRANS-1-BENZOYL-4-HYDROXY-L-PROLINE METHYL ESTER 2-BENZYL-7-BROMO-6-METHOXY-2-AZABICYCLO[2.2.1]HEPTANE N-BENZYL-L-PROLINE

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