ChemicalBook Product Catalog Organic Chemistry Inorganic acid Esters Diphenyl phosphate

Diphenyl phosphate

Diphenyl phosphate Basic information
Product Name:Diphenyl phosphate
Synonyms:DIPHENYL PHOSPHATE;PHOSPHORIC ACID DIPLHENYL ESTER;Phosphoric acid hydrogen diphenyl ester;Biphenyl Ester;Diphenyl phosphate,99%;diphenylhydrogenphosphate;phenylphosphate((pho)2(ho)po);Diphenyl phosphate, 98+%
CAS:838-85-7
MF:C12H11O4P
MW:250.19
EINECS:212-657-2
Product Categories:Aromatics;Metabolites & Impurities;Phosphorylating and Phosphitylating Agents;Biochemistry;Reagents for Oligosaccharide Synthesis;Organic Phosphates/Phosphites;Organic Building Blocks;Phosphorus Compounds;Aromatics, Metabolites & Impurities, Phosphorylating and Phosphitylating Agents
Mol File:838-85-7.mol
Diphenyl phosphate Structure
Diphenyl phosphate Chemical Properties
Melting point 62-66 °C (lit.)
Boiling point 280°C
density 0,76 g/cm3
refractive index 1.6250
Fp 4°C
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform (Slightly), Methanol (Slightly)
pka1.12±0.50(Predicted)
form Crystalline Powder
color White
Water Solubility Soluble in benzene. Insoluble in water.
BRN 1379164
InChIKeyASMQGLCHMVWBQR-UHFFFAOYSA-N
CAS DataBase Reference838-85-7(CAS DataBase Reference)
EPA Substance Registry SystemDiphenyl phosphate (838-85-7)
Safety Information
Risk Statements 36/37/38
Safety Statements 22-24/25
WGK Germany 3
RTECS TC5470000
TSCA Yes
HS Code 29190090
MSDS Information
ProviderLanguage
Diphenyl phosphate English
SigmaAldrich English
ACROS English
ALFA English
Diphenyl phosphate Usage And Synthesis
Chemical Propertieswhite crystalline powder
UsesDiphenyl phosphate can be used as an organic catalyst for the ring-opening polymerization (ROP) of renewable 5-alkyl δ-lactones. In combination with zinc iodide, it forms a novel initiating system for the living cationic polymerization of isobutyl vinyl ether.
UsesDiphenyl Phosphate is an organophosphate diester and metabolite of the flame retardant Triphenyl Phosphate (T808990) and also a metabolite of 2-Ethylhexyl diphenyl phosphate.
DefinitionChEBI: Diphenyl phosphate is an aryl phosphate.
Purification MethodsCrystallise it from CHCl3/pet ether. [Cherbuliez in Organo Phosphorus Compounds (Kosolapoff & Maier eds) Wiley Vol 6 pp 211-577 1973, Beilstein 6 IV 714.]
Diphenyl phosphate Preparation Products And Raw materials
Preparation Products4,4'-DIPYRIDYL SULFIDE
ISOPROPYLPHENYLDIPHENYL PHOSPHATE DIPHENYL PHOSPHORAMIDATE 4-ETHYL-3',3'',5',5''-TETRAMETHYLTRIPHENYL PHOSPHATE 1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate .beta.-D-Galactopyranose, 1,6-anhydro-3,4-O-(1-methylethylidene)-, diphenyl phosphate METHYL DIPHENYL PHOSPHATE TRIS(2,6-DICHLOROPHENYL) PHOSPHATE TRICRESYL ORTHOPHOSPHATE triphosphate .beta.-D-Galactopyranose, 1,6-anhydro-, 3,4-diacetate 2-(diphenyl phosphate) TRI-(P-TERT-BUTYLPHENYL) PHOSPHATE phosphate isopropyl diphenyl phosphate 2-BIPHENYLYL DIPHENYL PHOSPHATE FERRIC PHOSPHATE TRIS(4-NITROPHENYL) PHOSPHATE BENZO[D]ISOXAZOL-3-YL DIPHENYL PHOSPHATE,1,2-BENZISOXAZOL-3-YL-DIPHENYL PHOSPHATE MONOCRESYL DIPHENYL PHOSPHATE 10G [R]
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