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| Product Name: | FLUMIOXAZIN | | Synonyms: | 7-fluoro-6-(3,4,5,6-tetrahydrophthalimido)-4-(2-propynyl)-1,4-benzoxazin-3(2;sumisoya;1H-Isoindole-1,3(2H)-dione, 2-7-fluoro-3,4-dihydro-3-oxo-4-(2-propynyl)-2H-1,4-benzoxazin-6-yl-4,5,6,7-tetrahydro-;flumioxazin (bsi, draft iso, ansi);FLUMIOXAZIN STANDARD;flumioxazin (ISO) N-(7-fluoro-3,4-dihydro-3-oxo-4-prop-2-ynyl-2H-1,4-benzoxazin-6-yl)cyclohex-1-ene-1,2-dicarboxamide;N-(7-fluoro-3,4-dihydro-3-oxo-4-prop-2-ynyl-2H-1,4-benzoxazin-6-yl)cyclohex-1-ene-1,2-dicarboxamide ,flumioxazin (ISO);Flumioxazin Solution, 1000ppm | | CAS: | 103361-09-7 | | MF: | C19H15FN2O4 | | MW: | 354.33 | | EINECS: | | | Product Categories: | Agro-Products;Aromatics;Heterocycles | | Mol File: | 103361-09-7.mol |  |
| | FLUMIOXAZIN Chemical Properties |
| Melting point | 201.83-203.83° | | Boiling point | 644.4±55.0 °C(Predicted) | | density | d20 1.5132 g/ml | | storage temp. | 0-6°C | | solubility | DMSO (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly, Heated) | | pka | -0.01±0.20(Predicted) | | form | neat | | LogP | 2.550 | | EPA Substance Registry System | Flumioxazin (103361-09-7) |
| Hazard Codes | T,N | | Risk Statements | 61-50/53 | | Safety Statements | 53-45-60-61 | | RIDADR | UN 3077 9 / PGIII | | WGK Germany | 3 | | Hazardous Substances Data | 103361-09-7(Hazardous Substances Data) | | Toxicity | LD50 in rats (mg/kg): >5000 orally; >2000 dermally; LC50 (4 hr) in rats (mg/m3): >3930 by inhalation; LC50 (96 hr) in bluegill, rainbow trout (mg/l): >21, 2.3 (Yoshida). |
| | FLUMIOXAZIN Usage And Synthesis |
| Description | FLUMIOXAZIN is a benzoxazinones-type herbicide used on soybeans, peanuts, orchard fruits and other crop. It is a diphenyl ether group G herbicide that functioning through inhibiting the protoorphyrinogen oxidase. As a light-dependent peroxidising herbicide (LDPH), it takes effect by blocking heme and chlorophyll biosynthesis resulting in the accumulation of phototoxic porphyrins, leading to the membrane damage and further killing the weeds.
| | Uses | Herbicide. | | Definition | ChEBI: Flumioxazin is a benzoxazine that is N-(prop-2-yn-1-yl)-2H-1,4-benzoxazin-3(4H)-one which is substituted at position 6 by a 1,3-dioxo-1,3,4,5,6,7-hexahydro-2H-isoindol-2-yl group and at position 7 by a fluorine. A protoporphyrinogen oxidase inhibitor, it is used for the control of weeds in soya, peanuts, and a variety of vegetable and fruit crops. It has a role as a herbicide, an agrochemical, an EC 1.3.3.4 (protoporphyrinogen oxidase) inhibitor and a teratogenic agent. It is a benzoxazine, a terminal acetylenic compound, a dicarboximide and an organofluorine compound. | | Metabolic pathway | When the rats are given a single oral dose of 14C-S-
53482, seven metabolites are identified in the urine
and the feces. Alcohol derivatives and the acetoanilide
derivative are isolated from the urine, and three
sulfonic acid conjugates with a sulfonic acid group
incorporated into the double bond of the 3,4,5,6-
tetrahydrophthalimide moiety are isolated from the
feces. |
| | FLUMIOXAZIN Preparation Products And Raw materials |
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