ChemicalBook Product Catalog Catalyst and Auxiliary Precious Metal Catalysts [(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride

[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride

[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride Basic information
Product Name:[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride
Synonyms:[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride;[PdCl2{(R)-4-tolylbinap}]
CAS:191654-69-0
MF:C48H42Cl2P2Pd
MW:858.13
EINECS:
Product Categories:
Mol File:191654-69-0.mol
[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride Structure
[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride Chemical Properties
Melting point >300°C
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 26
WGK Germany 3
MSDS Information
[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride Usage And Synthesis
UsesCatalyst for:
  • Enantioselective preparation of hydroxydicarbonyls via aldol addition of pyruvates and diketones with ketene thioacetal
  • Stereoselective aldol condensation using trimethyl[[(phenyl)ethenyl]oxy]silane and benzaldehyde as reactants
  • Stereoselective preparation of naphthalenols via alkylative ring opening of oxabenzonorbornadienes with dialkylzinc

Reactant for:
  • Preparation of palladium bis(diphenylphosphino)binaphthyl aqua mononuclear and hydroxo-bridged dinuclear complexes
[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride Preparation Products And Raw materials
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