Ruthenium acetylacetonate

Ruthenium acetylacetonate Basic information
Product Name:Ruthenium acetylacetonate
Synonyms:RUTHENIUM(III) 2,4-PENTANEDIONATE;RUTHENIUM(III) ACETYLACETONATE;TRIS(ACETYLACETONATO)RUTHENIUM(III);TRIS(PENTANE-2,4-DIONATO)RUTHENIUM(III);2,4-PENTANEDIONE, RUTHENIUM(III) DERIVATIVE;4-pentanedionato-o,o’)-tris((oc-6-11)-rutheniu;Ruthenium(III) 2,4-pentanedionate~Tris(acetylacetonato)ruthenium(III)~Tris(2,4-pentanedionato)ruthenium(III);Rutheniumacetylacetonateredbrownxtl
CAS:14284-93-6
MF:C15H21O6Ru
MW:398.39
EINECS:238-193-0
Product Categories:Ru;chemical reaction,pharm,electronic,materials;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;metal beta-diketonate complexes;Metal Complexes;Ru (Ruthenium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds
Mol File:14284-93-6.mol
Ruthenium acetylacetonate Structure
Ruthenium acetylacetonate Chemical Properties
Melting point 260 °C (dec.)(lit.)
storage temp. Store below +30°C.
form Crystalline
color White
Water Solubility Soluble in most organic solvents such as acetone, chlorinated hydrocarbons, alcohols, cyclohexane and benzene. Insoluble in water.
InChIKeyRTZYCRSRNSTRGC-LNTINUHCSA-K
EPA Substance Registry SystemRuthenium, tris(2,4-pentanedionato-.kappa.O,.kappa.O')-, (OC-6-11)- (14284-93-6)
Safety Information
Hazard Codes Xi,T
Risk Statements 36/37/38
Safety Statements 26-36-24/25
WGK Germany 3
10
TSCA Yes
HS Code 28439000
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Ruthenium acetylacetonate Usage And Synthesis
Chemical Propertiesdark-red crystals
UsesPrecursor for the preparation of other compounds of ruthenium. Ruthenium(III) 2,4-pentanedionate is employed as a recyclable catalyst for certain organic transformations like the acetylation of phenols, alcohols, and amines under neat conditions. It is also used as a homogeneous catalyst, for example, in the hydrolysis of sodium borohydride and regiospecific tritiation of aromatic carboxylic acids. It is also used as a catalyst for enantioselective hydrogenation of acids such as aryl acrylic acid and aryl propenic acid.
Purification MethodsPurify the complex by recrystallisation from *benzene. [Wilkinson J Am Chem Soc 74 6146 1952, Beilstein 1 IV 3677.]
Ruthenium acetylacetonate Preparation Products And Raw materials
Bis(acetylacetonato)cobalt Aluminum acetylacetonate Acetylacetone Ethyl 2,4-dioxovalerate Cupric acetylacetonate Ferric acetylacetonate Zinc(II) acetylacetonate titanium (Ⅳ) acetylacetonate Acetone Ruthenium acetylacetonate 2,2-Bis(hydroxymethyl)-2,2',2''-nitrilotriethanol Tricine Ruthenium Pentane TRIS BUFFER SOLUTION PH 8.5, 1 L ACETYLACETONATE Tris(hydroxymethyl)aminomethane BUFFER SOLUTION PH = 6,00 (20 °C) (POTASSIUM DIHYDROGEN PHOSPHATE/SODIUM HYDROXIDE)

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