ChemicalBook Product Catalog Organic Chemistry Organometallic compounds Organomagnesium METHYLMAGNESIUM IODIDE

METHYLMAGNESIUM IODIDE

METHYLMAGNESIUM IODIDE Basic information
Product Name:METHYLMAGNESIUM IODIDE
Synonyms:METHYLMAGNESIUM IODIDE;MAGNESIUM METHYL IODIDE;iodomethyl-magnesiu;methylmagnesiumiodidesol.;Methylmagnesium Iodide (33% in Ethyl Ether, ca. 2mol/L);Methylmagnesium iodide solution;iodomethylmagnesium;METHYLMAGNESIUM IODIDE SOL., ~3 M IN DIE THYL ETHER
CAS:917-64-6
MF:CH3IMg
MW:166.24
EINECS:213-031-1
Product Categories:Grignard Reagent;Alkyl;Chemical Synthesis;Organic Bases;Organometallic Reagents;Synthetic Reagents;Classes of Metal Compounds;Grignard Reagents;Grignard Reagents & Alkyl Metals;AlkylChemical Synthesis;Grignard Reagents;Organic Bases;Organometallic Reagents;Synthetic Reagents;Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds
Mol File:917-64-6.mol
METHYLMAGNESIUM IODIDE Structure
METHYLMAGNESIUM IODIDE Chemical Properties
density 1.26 g/mL at 20 °C
Fp -40 °C
BRN 1209226
InChIKeyAUPXBVDHVRZMIB-UHFFFAOYSA-M
EPA Substance Registry SystemMagnesium, iodomethyl- (917-64-6)
Safety Information
Hazard Codes F+,C,F
Risk Statements 12-14/15-22-34-66-67-19-11
Safety Statements 16-26-36/37/39-43-45-7/8
RIDADR UN 3399 4.3/PG 1
WGK Germany 1
F 1-3-10
HazardClass 4.2
PackingGroup I
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
METHYLMAGNESIUM IODIDE Usage And Synthesis
Chemical PropertiesDark grey liquid
UsesAlkylating agent in organic synthesis, Grignardreagent.
UsesMethylmagnesium iodide solution can be used:
  • To prepare cis-1,2-dialkylcyclopropanols by treating with titanium(IV) alkoxide and carboxylic esters.
  • In stereospecific Ni catalyzed Kumada cross-coupling reactions of benzylic ethers.
  • To prepare 2,4-disubstituted selenochromenes by reacting with 1-benzoselenopyrylium salts.
  • In one of the key synthetic steps for the preparation of 7β-methyl-substituted 5-androstene derivatives from 3β-acetoxyandrost-5-en-17-one stereoselectively.

DefinitionAvailable as solution inether.
HazardFlammable, dangerous fire and explosionrisk.
METHYLMAGNESIUM IODIDE Preparation Products And Raw materials
Preparation ProductsS-METHYL THIOACETATE-->PINANOL 85-->1H-Indene, 1,3-dimethyl--->DELTA-8-THC-->2,3-dimethyl-1H-indene-->4,4-DIMETHYL HEPTANE-->DODECANE,3-METHYL--->1,2,3-TRIMETHYLNAPHTHALENE-->Ethanone, 1-(3,4-dihydro-2H-pyrrol-5-yl)- (9CI)-->2,5-DIMETHYL-2-HEXANOL-->1-Methylcyclobutanol-->2-METHYL-2-HEPTANOL-->1-CYCLOPROPYL-PROPAN-2-ONE-->2-(1-Adamantyl)propan-2-ol-->4,4'-VINYLIDENEBIS(N,N-DIMETHYLANILINE)-->METHYL HEPTAFLUOROPROPYL KETONE
ALLYLMAGNESIUM BROMIDE PHENYLMAGNESIUM BROMIDE Butylmagnesium chloride N-BUTYLMAGNESIUM BROMIDE ISOBUTYLMAGNESIUM BROMIDE ISOBUTYLMAGNESIUM CHLORIDE Methylmagnesium Bromide TERT-BUTYLMAGNESIUM CHLORIDE Vinylmagnesium chloride ISOPROPYLMAGNESIUM BROMIDE PHENYLMAGNESIUM IODIDE ethylmagnesium iodide Deuterated methyl magnesium iodide 3-THIENYLMAGNESIUM IODIDE 3-CHLORO-4-METHYLPHENYLMAGNESIUM IODIDE METHYLMAGNESIUM IODIDE trideutero-methylmagnesium iodide Magnesium
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