ChemicalBook Product Catalog Chemical Reagents Organic reagents Aliphatic aldehydes Ethyl glyoxalate

Ethyl glyoxalate

Ethyl glyoxalate Basic information
Product Name:Ethyl glyoxalate
Synonyms:Ethyl glyoxalate 100 liq;Ethyl oxoacetate Ethyl Glyoxylate Polymer form Ethyl Oxoacetate Polymer form Glyoxalic Acid Ethyl Ester Polymer form;GLYOXYLIC ACID ETHYL ESTER POLYMER FORM;GLYOXALIC ACID ETHYL ESTER POLYMER FORM;ETHYL OXOACETATE POLYMER FORM;ETHYL GLYOXYLATE POLYMER FORM;ETHYL GLYOXALATE;Ethyl glyoxalate, Approx. 50% in toluene
CAS:924-44-7
MF:C4H6O3
MW:102.09
EINECS:213-105-3
Product Categories:Aldehydes;Building Blocks;C1 to C6;C2 to C5;Carbonyl Compounds;Chemical Synthesis;Esters;Organic Building Blocks;bc0001
Mol File:924-44-7.mol
Ethyl glyoxalate Structure
Ethyl glyoxalate Chemical Properties
Boiling point 110°C
density 1.03 g/mL at 20 °C
refractive index 1.4750
Fp 7°C
storage temp. Refrigerator
solubility Chloroform, Ethyl Acetate
form Oil
color Clear Colorless
Water Solubility Immiscible with water.
Sensitive Air Sensitive
BRN 1209486
CAS DataBase Reference924-44-7(CAS DataBase Reference)
EPA Substance Registry SystemAcetic acid, oxo-, ethyl ester (924-44-7)
Safety Information
Hazard Codes F,Xn
Risk Statements 11-38-43-48/20-63-65-67
Safety Statements 36/37-62-16
RIDADR UN 1294 3/PG 2
WGK Germany 3
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29183000
MSDS Information
ProviderLanguage
Ethyl oxoacetate English
SigmaAldrich English
ALFA English
Ethyl glyoxalate Usage And Synthesis
Chemical PropertiesClear colorless to slightly yellow solution
UsesEthyl glyoxylate is widely used as an intermediate in the synthesis of pharmaceuticals (high reactivity of aldehyde function). It is used in the synthesis of a biodegradable polymer, poly(ethyl glyoxylate). It is actively involved in the Friedel-Crafts alkylation reactions with thiophenes to give the corresponding secondary alcohols.
DefinitionChEBI: The ethyl ester of glyoxylic acid.
Synthesis Reference(s)Tetrahedron Letters, 24, p. 2223, 1983 DOI: 10.1016/S0040-4039(00)81889-4
Ethyl glyoxalate Preparation Products And Raw materials
Preparation ProductsMETHYL-2-CHLOROOXAZOLE-5-CARBOXYLATE-->2-Chloroquinoxaline-->2-Bromoquinoxaline-->5-amino-1,3,4-thiadiazole-2-carboxylic acid-->2-QUINOXALINETHIOL-->5-AMINO-1,3,4-THIADIAZOLE-2-CARBOXYLIC ACID ETHYL ESTER-->ETHYL OXAZOLE-5-CARBOXYLATE-->Monoethyl fumarate-->1H-BENZOIMIDAZOLE-2-CARBOXYLIC ACID ETHYL ESTER-->Methyl 5-oxazolecarboxylate-->7-NITRO-2(1H)-QUINOXALINONE-->Diethyl malate-->ETHYL 3-PHENYL-2-(PIPERIDIN-1-YL)PROPANOATE-->5-CHLORO-2-BENZOTHIAZOLECARBOXYLIC ACID ETHYL ESTER-->2,3-Dichloro-α-(2,3-dichloro-4-Methoxyphenyl)-4-Methoxy-benzeneacetic Acid Ethyl Ester
BUPIRIMATE (1R)-(-)-Menthyl glyoxylate hydrate 2,4-DIMETHYL, 1,3-DIOXALONE Ethylboronic acid pinacol ester Methyl 2-oxoacetate Ethyldicyclohexylbenzoic acid 2-Ethynyl-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane 2-[(Acetyloxy)methoxy]ethyl acetate (4-Nitrophenyl)methyl 3-oxobutanoate Pinacol vinylboronate ETHYL 4-CHLOROBENZOYLFORMATE ETHYL THIOPHENE-2-GLYOXYLATE SODIUM GLYOXYLATE Ethyl cyanoglyoxylate-2-oxime Ethyl 2-(2-aminothiazol-4-yl)glyoxylate ETHYL 1-PIPERIDINEGLYOXYLATE Ethyl 4-bromobenzoylformate (6-CHLORO-PYRIDIN-3-YL)-OXO-ACETIC ACID ETHYL ESTER
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