2-Methyl-3-nitropyridine

2-Methyl-3-nitropyridine Basic information
Product Name:2-Methyl-3-nitropyridine
Synonyms:3-NITRO-2-PICOLINE;3-NITRO-2-METHYLPYRIDINE;2-METHYL-3-NITROPYRIDINE;2-Methyl-3-nitropyri;Pyridine, 2-methyl-3-nitro- (9CI);3-Nitro-2-methylpyridine 3-Nitro-2-picoline;2-METHYL-3-NITROPYRIDINE 95%;3-NITROPICOLINE
CAS:18699-87-1
MF:C6H6N2O2
MW:138.12
EINECS:805-108-9
Product Categories:Pyridines;Pyridine;NITRO
Mol File:18699-87-1.mol
2-Methyl-3-nitropyridine Structure
2-Methyl-3-nitropyridine Chemical Properties
Melting point 32-33°
Boiling point 86°C/5mmHg(lit.)
density 1.246±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility soluble in Methanol
form powder to lump
pka1.92±0.10(Predicted)
color Light yellow to Brown
InChIKeyCCFGTKQIRWHYTB-UHFFFAOYSA-N
CAS DataBase Reference18699-87-1(CAS DataBase Reference)
Safety Information
Hazard Codes Xn
Risk Statements 22
HazardClass IRRITANT
HS Code 2933399990
MSDS Information
2-Methyl-3-nitropyridine Usage And Synthesis
Uses2-Methyl-3-nitropyridine is used as a starting reagent to synthesize 3-substituted-4 or 6-azaindoles, and is also used as a reagent to prepare 3-azaindolyl-4-arylmalemides (compounds that exhibit antiproliferative activity).
Synthesis Reference(s)Tetrahedron, 54, p. 6311, 1998 DOI: 10.1016/S0040-4020(98)00328-7
Journal of Heterocyclic Chemistry, 29, p. 359, 1992 DOI: 10.1002/jhet.5570290213
Synthetic Communications, 20, p. 2965, 1990 DOI: 10.1080/00397919008051513
2-Methyl-3-nitropyridine Preparation Products And Raw materials
Preparation Products2-Methyl-5-nitropyridine-->3-Amino-2-picoline-->2-Picoline-->3-broMo-1H-pyrrolo[3,2-b]pyridine-2-carboxylic acid-->2-Methyl-3-nitropyridine N-oxide-->Ethenamine, N,N-dimethyl-2-(3-nitro-2-pyridinyl)-
Methylparaben nitrotoluene Bensulfuron methyl Parathion-methyl 2-Methyl-4-nitropyridine 2-Methyl-3-nitropyridine 21203-68-9 2-Methyl-5-nitropyridine,2-Methyl-5-nitropyridine Hydrochloride Azamethiphos ETHYL 2-CHLORO-3-CYANO-6-METHYL-5-NITROPYRIDINE-4-CARBOXYLATE 2-Bromo-5-nitropyridine Kresoxim-methyl 2,6-Lutidine 2,4,6-Collidine Thiophanate-methyl Methyl acrylate Methyl acetate Methyl bromide METSULFURON METHYL

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