Bis(3-allyl-4-hydroxyphenyl)sulfone

Bis(3-allyl-4-hydroxyphenyl)sulfone Basic information
Product Name:Bis(3-allyl-4-hydroxyphenyl)sulfone
Synonyms:Bis(3-allyl-4-hydroxyphenyl)sulfone;2,2'-diallyl-4,4'-sulfonyldiphenol;4,4'-Sulfonylbis(2-allylphenol);4,4'-Sulfonylbis[2-(2-propenyl)phenol];Bis(4-hydroxy-3-allylphenyl) sulfone;TGSH;4-(4-hydroxy-3-prop-2-enylphenyl)sulfonyl-2-prop-2-enylphenol;4-(4-hydroxy-3-prop-2-enylphenyl)sulfonyl-2-prop-2-enylph
CAS:41481-66-7
MF:C18H18O4S
MW:330.4
EINECS:411-570-9
Product Categories:
Mol File:41481-66-7.mol
Bis(3-allyl-4-hydroxyphenyl)sulfone Structure
Bis(3-allyl-4-hydroxyphenyl)sulfone Chemical Properties
Melting point 138.5 °C(Solv: toluene (108-88-3))
Boiling point 544.5±50.0 °C(Predicted)
density 1.253±0.06 g/cm3(Predicted)
storage temp. -20°C Freezer
solubility DMSO (Sparingly), Methanol (Slightly)
pka7.22±0.20(Predicted)
form Solid
color White to Off-White
InChIInChI=1S/C18H18O4S/c1-3-5-13-11-15(7-9-17(13)19)23(21,22)16-8-10-18(20)14(12-16)6-4-2/h3-4,7-12,19-20H,1-2,5-6H2
InChIKeyMTMKZABGIQJAEX-UHFFFAOYSA-N
SMILESS(C1=CC=C(O)C(CC=C)=C1)(C1=CC=C(O)C(CC=C)=C1)(=O)=O
EPA Substance Registry SystemPhenol, 4,4'-sulfonylbis[2-(2-propenyl)- (41481-66-7)
Safety Information
Hazard Codes Xi,N
Risk Statements 43-51/53
Safety Statements 24-37-61
MSDS Information
Bis(3-allyl-4-hydroxyphenyl)sulfone Usage And Synthesis
Chemical PropertiesWhite to Off-White Solid    
Chemical PropertiesThe preparation of Bis(3-allyl-4-hydroxyphenyl)sulfone is as follows:4,4'-diallyl diphenyl sulfone (40 g, 0.12 mol) and methyl glycine diacetic acid (0.4 g) were added to 100 mL (95.36 g) of diethylene glycol monobutyl ether under nitrogen protection.The reaction was stirred and heated in a 198-200 ° C oil bath for 7 hours. After the reaction was completed, the solvent was recovered, and the residue was poured into 100 mL of 10% NaOH (110 g) solution, stirred and dissolved, and heated to 80 ° C for 15 minutes after adding activated carbon. After filtration, the aqueous phase was cooled to room temperature, and the pH was adjusted to about 8.5 with 30% H 2 SO 4 while stirring. The ice water bath was maintained at a temperature not higher than 30 ° C, filtered, and dried to obtain 38.5 g of a white solid, yield 96.2%, purity 97.5%.

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UsesBis(3-allyl-4-hydroxyphenyl)sulfone has been used in the preparation of microcapsules for light-thermal sensitive imaging system.
DefinitionChEBI: 4,4'-sulfonylbis[2-(prop-2-en-1-yl)phenol] is a sulfonic acid derivative.
Bis(3-allyl-4-hydroxyphenyl)sulfone Preparation Products And Raw materials
Raw materials1,1'-Sulfonylbis[4-(prop-2-en-1-yloxy)benzene-->ALLYL TOLUENE-4-SULFONATE-->Allyl chloride-->Bis(4-hydroxyphenyl) Sulfone
4,4'-Diaminodiphenylsulfone 4-Hydroxy-4'-isopropoxydiphenylsulfone Bis(4-hydroxyphenyl) Sulfone 4-[(4-Benzyloxyphenyl)sulfonyl]phenol Benzenesulfonamide,4-methyl-N-[[[3-[[(4-methylphenyl)sulfonyl]oxy]phenyl]amino]carbonyl]- Ethylene glycol diphenyl ether 2-Allylphenol

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