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TIN(II) IODIDE

TIN(II) IODIDE Basic information
Product Name:TIN(II) IODIDE
Synonyms:TIN(II) IODIDE;TIN(+2)IODIDE;TIN IODIDE;STANNOUS IODIDE;diiodotin;SnI2;stannousdiiodide;Tin iodide (SnI2)
CAS:10294-70-9
MF:I2Sn
MW:372.52
EINECS:233-667-3
Product Categories:Crystal Grade Inorganics;Metal and Ceramic Science;Salts;Tin Salts;TinMetal and Ceramic Science;metal halide
Mol File:10294-70-9.mol
TIN(II) IODIDE Structure
TIN(II) IODIDE Chemical Properties
Melting point 320 °C (lit.)
Boiling point 714 °C (lit.)
density 5.28 g/mL at 25 °C (lit.)
Fp 720°C
solubility Soluble in benzene, carbon disulfide, chloroform, and solutions of alkali chlorides and iodides.
form Powder
Specific Gravity5.28
color orange to red
Water Solubility Soluble in benzene, carbon disulfide, chloroform, and solutions of alkali chlorides and iodides. Decomposes in water
Sensitive Air & Moisture Sensitive
Hydrolytic Sensitivity7: reacts slowly with moisture/water
Merck 14,8785
Exposure limitsACGIH: TWA 2 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 2 mg/m3
CAS DataBase Reference10294-70-9(CAS DataBase Reference)
EPA Substance Registry SystemTin iodide (SnI2) (10294-70-9)
Safety Information
Hazard Codes T
Risk Statements 61-20/21/22-36/37/38-42/43
Safety Statements 53-22-26-36/37/39-45
RIDADR UN 3260 8/PG 2
WGK Germany 3
RTECS XQ3650000
TSCA Yes
HazardClass 8
PackingGroup III
HS Code 28276000
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
TIN(II) IODIDE Usage And Synthesis
Chemical Propertiesreddish orange powder(s); moisture sensitive; enthalpy of vaporization 105kJ/mol [CRC10] [STR93]
UsesTin(II) iodide is used to prepare organic-inorganic perovskite thin films which exhibit uniform surfaces and strong photoluminescence. It finds application as an analytical reagent in the determination of rhodium and iridium by spectrophotometry. It is also involved in the synthesis of CH3(CH2)11NH3]SnI3 which is a hybrid semiconductor with MoO3 type tin(II) iodide layers.
Safety ProfilePoison by intravenous route. When heated to decomposition it emits toxic fumes of I-. See also IODIDES and TIN COMPOUNDS.
TIN(II) IODIDE Preparation Products And Raw materials
TIN (II) BROMIDE DIETHYLTINDIIODIDE TIN(II) IODIDE PHOSPHONIUM IODIDE DIALLYL ITACONATE TIN(IV) IODIDE Stannous Iodide
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