POLY(VINYL FORMAL)

POLY(VINYL FORMAL) Basic information
Product Name:POLY(VINYL FORMAL)
Synonyms:polyvinylformalstaplefiber;Vinylacetate,polymerwithformaldehyde;FORMVAR RESIN;FORMVAR 15/95;FORMVAR 15/95 RESIN;FORMVAR 15/95 (POLY[VINYL FORMAL]), 0.5% SOLN. IN ETHYLENE DICHLORIDE;vinyl formal homopolymer;PVF;PVFO
CAS:9003-33-2
MF:C5H8O2
MW:100.11582
EINECS:
Product Categories:Hydrophobic Polymers;Polymer Science;Vinyl Acetals;Polymers;Hydrophobic Polymers;Materials Science;Polymer Science;Vinyl Acetals
Mol File:9003-33-2.mol
POLY(VINYL FORMAL) Structure
POLY(VINYL FORMAL) Chemical Properties
Melting point 85-120 °C
density 1.23 g/mL at 25 °C (lit.)
refractive index n20/D 1.502
solubility Soluble in acetone, chloroform, dioxane, THF
form powder
Specific Gravity1.23
EPA Substance Registry SystemEthene, 1,1'-[methylenebis(oxy)]bis-, homopolymer (9003-33-2)
Safety Information
WGK Germany 3
TSCA Yes
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
POLY(VINYL FORMAL) Usage And Synthesis
UsesIt is used in the anomalous sorption and pervaporation of aqueous organic mixtures by poly(vinyl acetal) membranes. Poly(vinyl formal) is mainly used in three general applications wire coatings, surface coatings and adhesives. The first and extensive application of poly(vinyl formal) is in the manufacture of a tough, adhesive and heat resistant wire enamel.
PreparationPoly(vinyl formal) was developed by General Electric as a wire coating and the early process involved direct reaction of a mixture of poly(vinyl acetate), glacial acetic acid, formalin and concentrated sulfuric acid at 70°C. After the desired degree of polymerization is obtained, ammonium hydroxide is added to bring the pH to about 9-10. The reaction mixture is poured into water to precipitate the poly(vinyl formal). Poly(vinyl formais) have also been used as fibers.
POLY(VINYL FORMAL) Preparation Products And Raw materials
Poly(ethyl vinyl ether) POLY(VINYL METHYL ETHER) Poly(vinyl stearyl ether) POLY(VINYL ACETATE) POLY(VINYL METHYL KETONE) POLY(VINYL FORMAL) Polyvinylidene fluoride POLY(VINYL STEARATE) POLY(VINYL CINNAMATE) POLY(VINYL FORMAL) Interior wall coating 801 Poly(vinyl formal-acetal) resin Polyvinyl formal adhesive for construction 107 FORMVAR(R) polyvinyl formal cement floor paint Poly(vinyl alcohol) polyvinyl formal mastic floor paint

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