(-)-DI[(1R)-MENTHYL] FUMARATE

(-)-DI[(1R)-MENTHYL] FUMARATE Basic information
Product Name:(-)-DI[(1R)-MENTHYL] FUMARATE
Synonyms:(-)-DI[(1R)-MENTHYL] FUMARATE;(-)-DIMENTHYL FUMARATE;Bis(2-isopropyl-5-methylcyclohexyl) (2E)-2-butenedioate;Menthol, fumarate (2:1), (1R,3R,4S)-;(E)-2-Butenedioic acid bis[(1R)-5β-methyl-2α-isopropylcyclohexan-1β-yl] ester;Fumaric acid bis[(1R)-2α-isopropyl-5β-methylcyclohexane-1β-yl] ester;Fumaric acid bis[(1R,1β,4S)-p-menthane-3β-yl] ester;Fumaric acid bis[(1R,1β,4α)-p-menthane-3β-yl] ester
CAS:34675-24-6
MF:C24H40O4
MW:392.57
EINECS:
Product Categories:DID - DINChiral Building Blocks;Alphabetic;D;Esters;Organic Building Blocks
Mol File:34675-24-6.mol
(-)-DI[(1R)-MENTHYL] FUMARATE Structure
(-)-DI[(1R)-MENTHYL] FUMARATE Chemical Properties
Melting point 59-61 °C (lit.)
Boiling point 211 °C/5 mmHg (lit.)
density 0.9985 (rough estimate)
refractive index 1.4460 (estimate)
form Low Melting Solid or Powder
color Colorless to off-white
optical activity[α]20/D 102°, c = 1 in chloroform
BRN 2568525
Safety Information
Safety Statements 22-24/25
WGK Germany 3
MSDS Information
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SigmaAldrich English
(-)-DI[(1R)-MENTHYL] FUMARATE Usage And Synthesis
Uses(-)-Dimenthyl Fumarate is used as a reagent in organic chemical synthesis of several compounds including that of pentacyclic steroids via tandem stille coupling. It was also used in synthesis of Lobucavir (L469360) which is an antiviral agent.
(-)-DI[(1R)-MENTHYL] FUMARATE Preparation Products And Raw materials
HEPTYL-CROTONATE (1S)-(+)-MENTHYL ACETATE DIOCTYL FUMARATE DIPENTYL FUMARATE DIISOPROPYL FUMARATE Diisobutyl fumarate Cyclohexyl acrylate (-)-DI[(1R)-MENTHYL] FUMARATE D-MENTHYL ACRYLATE L-MENTHYL ACETATE Isobutyl 2-butenoate DI-N-HEXYL FUMARATE Diethyl fumarate Dimethyl fumarate Monoethyl fumarate 2-ETHYLBUTYL ACRYLATE Dibutyl fumarate L-MENTHYL ACRYLATE

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