ChemicalBook Product Catalog Chemical Reagents Organic reagents Cyanide / nitrile (PHENYLSULFONYL)ACETONITRILE

(PHENYLSULFONYL)ACETONITRILE

(PHENYLSULFONYL)ACETONITRILE Basic information
Product Name:(PHENYLSULFONYL)ACETONITRILE
Synonyms:AURORA KA-6231;BENZENESULFONYLACETONITRILE;BENZENESULPHONYLACETONITRILE;CYANOMETHYLSULFONYLBENZENE;(PHENYLSULFONYL)ACETONITRILE;(PHENYLSULPHONYL)ACETONITRILE;Acetonitrile, (phenylsulfonyl)-;Acetonitrile, 2-phenylsulfonyl-
CAS:7605-28-9
MF:C8H7NO2S
MW:181.21
EINECS:231-515-0
Product Categories:C8 to C9;Cyanides/Nitriles;Nitrogen Compounds
Mol File:7605-28-9.mol
(PHENYLSULFONYL)ACETONITRILE Structure
(PHENYLSULFONYL)ACETONITRILE Chemical Properties
Melting point 112-114 °C(lit.)
Boiling point 398.5±34.0 °C(Predicted)
density 1.284±0.06 g/cm3 (20 ºC 760 Torr)
refractive index 1.5650 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility soluble in Methanol
form powder to crystal
color White to Almost white
BRN 640716
InChIKeyZFCFFNGBCVAUDE-UHFFFAOYSA-N
CAS DataBase Reference7605-28-9(CAS DataBase Reference)
Safety Information
Hazard Codes T,Xi
Risk Statements 23/24/25-36/37/38
Safety Statements 36/37/39-45-36-26
RIDADR 3276
WGK Germany 3
Hazard Note Irritant
HazardClass 6.1
PackingGroup III
HS Code 2930909899
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
(PHENYLSULFONYL)ACETONITRILE Usage And Synthesis
Chemical PropertiesWhite to off-white-greyish crystalline powder
Uses(Phenylsulfonyl)acetonitrile was used in the synthesis of pyridines, chromenes and thiophene derivatives based on sulfones.
Synthesis Reference(s)Synthesis, p. 56, 1987 DOI: 10.1055/s-1987-27843
General DescriptionCondensation reaction of (phenylsulfonyl)acetonitrile with benzaldehyde in water in heterogeneous phase in the presence and absence of anionic and cationic surfactants has been studied. Dehydrative alkylation of alcohols with (phenylsulfonyl)acetonitrile under modified Mitsunobu conditions has been investigated.
(PHENYLSULFONYL)ACETONITRILE Preparation Products And Raw materials
Preparation Products2,4-Pentadienenitrile, 5-phenyl-2-(phenylsulfonyl)-, (E,E)- (9CI)-->4,6-DIMETHYL-3-(PHENYLSULFONYL)-2(1H)-PYRIDINONE-->1-(PHENYLSULFONYL)CYCLOPROPANECARBONITRILE-->2-Thiopheneacetonitrile, α-(phenylsulfonyl)--->2-(PHENYLSULFONYL)-3-(3-PYRIDYL)PROP-2-ENENITRILE
AKOS BBS-00002840 2,4-DICHLOROBENZENESULPHONYLACETONITRILE 2-((4-CHLOROPHENYL)SULFONYL)-3-(4-METHOXYPHENYL)PROP-2-ENENITRILE 2-((4-CHLOROPHENYL)SULFONYL)-3-(2-THIENYL)PROP-2-ENENITRILE SODIUM (4-CHLOROPHENYL)[2-NITRILO(OXIDO)ETHANIMIDOYL]DIOXO-LAMBDA6-SULFANE (PHENYLSULFONYL)ACETONITRILE 2-(2-NAPHTHYLSULFONYL)ACETONITRILE 3-ETHOXY-2-(2-NAPHTHYLSULFONYL)ACRYLONITRILE 3-[(4-CHLORO-6-METHYLPYRIMIDIN-2-YL)AMINO]-2-[(4-CHLOROPHENYL)SULFONYL]ACRYLONITRILE 2-((4-CHLOROPHENYL)SULFONYL)-3-(PYRIMIDIN-2-YLAMINO)PROP-2-ENENITRILE 4-CHLOROPHENYLSULFONYLACETONITRILE 2-[(4-CHLOROPHENYL)SULFONYL]-2-HYDROXYIMINOACETONITRILE 3-ETHOXY-2-(PHENYLSULFONYL)ACRYLONITRILE 4-(Methylphenyl)sulfonylacetonitrile 2-((4-CHLOROPHENYL)SULFONYL)-3-ETHOXYPROP-2-ENENITRILE 2-HYDROXYIMINO-2-(PHENYLSULFONYL)ACETONITRILE 4-ISOPROPYLBENZENESULPHONYLACETONITRILE 3-AMINO-2-[(4-CHLOROPHENYL)SULFONYL]ACRYLONITRILE
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