ChemicalBook Product Catalog Chemical Reagents Organic reagents Esters Ethyl compound ETHYL PHENYLPROPIOLATE

ETHYL PHENYLPROPIOLATE

ETHYL PHENYLPROPIOLATE Basic information
Product Name:ETHYL PHENYLPROPIOLATE
Synonyms:2-Propynoic acid, 3-phenyl-, ethyl ester;3-phenyl-2-propynoicaciethylester;Ethyl phenylpropriolate;Ethyl phenylpropynoate;Ethylphenylpropiolate,98+%;3-Phenyl-2-propynoicacidethylester;ETHYL-3-PHENYLPROPIOLATE 98%;Ethyl phenylpropiolate, 98% 25GR
CAS:2216-94-6
MF:C11H10O2
MW:174.2
EINECS:218-703-8
Product Categories:Building Blocks;C10 to C11;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;Acetylenes;Acetylenic Carboxylic Acids & Their Derivatives;C10 to C11;Carbonyl Compounds;Esters
Mol File:2216-94-6.mol
ETHYL PHENYLPROPIOLATE Structure
ETHYL PHENYLPROPIOLATE Chemical Properties
Melting point 149-150 °C
Boiling point 260-270 °C(lit.)
density 1.055 g/mL at 25 °C(lit.)
refractive index n20/D 1.552(lit.)
Fp >110°C
storage temp. 2-8°C
form Liquid
color Clear yellow
Specific Gravity1.055
Water Solubility Insoluble in water.
BRN 639637
InChIKeyACJOYTKWHPEIHW-UHFFFAOYSA-N
CAS DataBase Reference2216-94-6(CAS DataBase Reference)
EPA Substance Registry SystemEthyl phenylpropiolate (2216-94-6)
Safety Information
Risk Statements 36/38
Safety Statements 24/25
WGK Germany 3
RTECS UE0110000
HS Code 29163990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
ETHYL PHENYLPROPIOLATE Usage And Synthesis
Chemical Propertiesclear yellowish liquid
UsesEthyl phenylpropiolate, is an important organic intermediate. It is also used as an intermediate in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff.
Synthesis Reference(s)The Journal of Organic Chemistry, 50, p. 2372, 1985 DOI: 10.1021/jo00213a034
Synthesis, p. 498, 1987 DOI: 10.1055/s-1987-27983
General DescriptionClear pale yellow liquid.
Air & Water ReactionsInsoluble in water.
Reactivity ProfileEsters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.
Fire HazardETHYL PHENYLPROPIOLATE is combustible.
ETHYL PHENYLPROPIOLATE Preparation Products And Raw materials
Preparation ProductsLevofloxacin-->Loxoprofen-->Tetraphenylcyclopentadienone-->3-PHENYL-2-PROPYN-1-OL-->7-phenyl-4H,5H-[1,2,4]triazolo[1,5-a]pyrimidin-5-one-->3-Hydroxy-5-phenyl-1H-pyrazole
(4-FLUORO-PHENYL)-PROPYNOIC ACID ETHYL ESTER (4-HYDROXY-PHENYL)-PROPYNOIC ACID ETHYL ESTER M-TOLYL-PROPYNOIC ACID ETHYL ESTER (3-NITRO-PHENYL)-PROPYNOIC ACID ETHYL ESTER (3-TRIFLUOROMETHYL-PHENYL)-PROPYNOIC ACID ETHYL ESTER (4-METHOXY-PHENYL)-PROPYNOIC ACID ETHYL ESTER (2-CHLORO-PHENYL)-PROPYNOIC ACID ETHYL ESTER (3-FLUORO-PHENYL)-PROPYNOIC ACID ETHYL ESTER (3-HYDROXY-PHENYL)-PROPYNOIC ACID ETHYL ESTER P-TOLYL-PROPYNOIC ACID ETHYL ESTER (4-NITRO-PHENYL)-PROPYNOIC ACID ETHYL ESTER (3-CHLORO-PHENYL)-PROPYNOIC ACID ETHYL ESTER (2-METHOXY-PHENYL)-PROPYNOIC ACID ETHYL ESTER O-TOLYL-PROPYNOIC ACID ETHYL ESTER (4-CHLORO-PHENYL)-PROPYNOIC ACID ETHYL ESTER (2-HYDROXY-PHENYL)-PROPYNOIC ACID ETHYL ESTER (4-TRIFLUOROMETHYL-PHENYL)-PROPYNOIC ACID ETHYL ESTER (3-METHOXY-PHENYL)-PROPYNOIC ACID ETHYL ESTER
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