1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE

1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE Basic information
Product Name:1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE
Synonyms:1,2-Bis(triMethylsiloxy)cyclobutene >=95%;BIS(TRIMETHYLSILOXY)CYCLOBUTENE;1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE;1,2-BIS(TRIMETHYLSILOXY)CYCLOBUTENE PURUM 95+ % (GC);1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE, 9 5+%;1,2-Bis(trimethylsiloxy)cyclobutenepurum;95+%(gc);BIS(TRIMETHYLSILOXY)CYCLOBUTENE ,95%
CAS:17082-61-0
MF:C10H22O2Si2
MW:230.45
EINECS:
Product Categories:Cyclobutanes & Cyclobutenes;Monoalkoxysilanes;Si (Classes of Silicon Compounds);Silicon Compounds (for Synthesis);Simple 4-Membered Ring Compounds;Si-O Compounds;Synthetic Organic Chemistry;Enol Ethers;Organic Building Blocks;Oxygen Compounds
Mol File:17082-61-0.mol
1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE Structure
1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE Chemical Properties
Boiling point 58-59 °C2 mm Hg(lit.)
density 0.897 g/mL at 25 °C(lit.)
refractive index n20/D 1.435(lit.)
Fp 142 °F
storage temp. Inert atmosphere,2-8°C
form clear liquid
color Colorless to Light yellow
Specific Gravity0.87
Hydrolytic Sensitivity7: reacts slowly with moisture/water
BRN 1367530
InChIKeyWOBRFSDEZREQAB-UHFFFAOYSA-N
CAS DataBase Reference17082-61-0(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
RIDADR 1993
WGK Germany 3
10-21
TSCA No
HS Code 2931.90.6000
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE Usage And Synthesis
Chemical Propertiesclear colorless liquid
Uses1,2-Bis(trimethylsilyloxy)cyclobutene is a useful chemical reactant used in the preparation and biological activity of serine and threonine β-lactones as inhibitors of hepatitis A virus 3C cysteine proteinase.
General DescriptionPhotocycloaddition of 2-cyclohexenones to 1,2-bis(trimethyl-siloxy)cyclobutene has been studied. It undergoes Aldol condensation reaction with carbonyl compounds. It reacts with Br2 to give cyclobutanedione.
1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE Preparation Products And Raw materials
Preparation Products2-(benzyloxy)cyclobutan-1-one-->2-Methyl-1,3-cyclopentanedione-->3-HYDROXY-2-PHENYLCYCLOPENT-2-ENONE
N,N-Dimethyltrimethylsilylamine (N,N-DIMETHYLAMINO)TRIETHYLSILANE tert-Butyldimethylsilyl chloride (N,N-DIMETHYLAMINO)DIMETHYLCHLOROSILANE VINYLOXYTRIMETHYLSILANE 1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE ISOPROPENYLOXYTRIMETHYLSILANE Trimethyl(propoxy)silane

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