2-Chloroacrylonitrile

2-Chloroacrylonitrile Basic information

Product Name:	2-Chloroacrylonitrile
Synonyms:	1-Chloroaerylonitrile;2-CHLORACRYLONITRIL;2-CHLOROACRYLONITRILE;2-CHLOROCYANOETHYLENE;2-CHLOROACRYLONITRILE, STAB.;2-Chloroacrylonitrile, stabilized, 99%;2-PROPENONITRLLE;2-Chloroacrylonitrile (stabilized with HQ)
CAS:	920-37-6
MF:	C3H2ClN
MW:	87.51
EINECS:	213-055-2
Product Categories:	Organic Building Blocks;Aliphatics;Boron, Nitrile, Thio,& TM-Cpds;Nitriles;C1 to C5;Cyanides/Nitriles;Nitrogen Compounds;Miscellaneous Reagents;Building Blocks;C1 to C5;Chemical Synthesis;Nitrogen Compounds
Mol File:	920-37-6.mol

2-Chloroacrylonitrile Chemical Properties

Melting point	−65 °C(lit.)
Boiling point	88-89 °C(lit.)
density	1.096 g/mL at 25 °C(lit.)
refractive index	n20/D 1.429(lit.)
Fp	44 °F
storage temp.	Inert atmosphere,2-8°C
solubility	Chloroform, Ethyl Acetate, Methanol (Very Slightly)
form	Liquid
color	Clear colorless to yellow
BRN	773744
InChIKey	OYUNTGBISCIYPW-UHFFFAOYSA-N
CAS DataBase Reference	920-37-6(CAS DataBase Reference)
NIST Chemistry Reference	2-Propenenitrile, 2-chloro-(920-37-6)
EPA Substance Registry System	2-Chloroacrylonitrile (920-37-6)

Safety Information

Hazard Codes	F,T+,T,N
Risk Statements	45-24-26/28-34-43-50-40-36/37/38-28-23/24-11
Safety Statements	53-26-36/37/39-45-61-28A-16-1-28
RIDADR	UN 3383 6.1/PG 1
WGK Germany	3
RTECS	AT5525000
Hazard Note	Flammable/Very Toxic
HazardClass	3.1
PackingGroup	II
HS Code	29269095

MSDS Information

Provider	Language
alpha-Chloroacrylonitrile	English
SigmaAldrich	English
ACROS	English

2-Chloroacrylonitrile Usage And Synthesis

Chemical Properties	colorless to light yellow liqui
Uses	Common reagent in cycloaddition reactions.1,2
Uses	2-Chloroacrylonitrile (cas# 920-37-6) is a compound useful in organic synthesis.
General Description	A liquid. Boiling point 190-192°F (88-89°C). Density 1.096 g / cm3. Flash point 44°F. Highly toxic.
Air & Water Reactions	Highly flammable.
Reactivity Profile	2-Chloroacrylonitrile readily polymerizes, and copolymerizes with other unsaturated monomers .
Health Hazard	Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Safety Profile	Suspected carcinogen. Poison by intravenous route. A powerful irritant. A dangerous fire hazard when exposed to heat or flame. To fight fire, use water, dry chemical, CO2, foam. When heated to decomposition it emits very toxic fumes of Cl-, NOx, and CN-. See also NITRILES.

2-Chloroacrylonitrile Preparation Products And Raw materials

Raw materials	Polymerization inhibitor
Preparation Products	FUSARIC ACID-->5-BUTYLPYRIDINE-2-CARBONITRILE-->4-BENZYL-MORPHOLINE-2-CARBOXYLIC ACID-->4-Chlorothieno[3,2-d]pyrimidine-->2-Cyanopiperazine-->METHYL 3-CHLOROTHIOPHENE-2-CARBOXYLATE-->THIENO[3,2-D]PYRIMIDIN-4(3H)-ONE-->ETHYL 3-AMINOTHIOPHENE-2-CARBOXYLATE-->PENTAFLUOROTHIOPHENOL

(Z)-3-Chloroacrylonitrile 3-TERT-BUTYL-3-CHLOROACRYLONITRILE 2-CHLOROACRYLONITRILE SOLUTION 1000UG/ML IN METHANOL 1ML 2-Chloroacrylonitrile 3-Chloroacrylonitrile 2-CHLOROACRYLONITRILE SOLUTION 1000UG/ML IN METHANOL 5X1ML Chloroacetonitrile ALPHA,BETA-DICHLOROACRYLONITRILE 2-Chloroacrylic acid E-3-AMINO-2-CHLORO-4,4,4-TRIFLUOROBUT-2-ENE NITRILE TRICHLOROACRYLONITRILE 3-(4-BROMOPHENYL)-3-CHLOROACRYLONITRILE 2-CHLOROACRYLONITRILE SOLUTION 1000UG/ML IN METHANOL 5ML Acrylonitrile 3-TERT-BUTYL-3-CHLOROACRYLONITRILE 95+% Diethylstilbestrol Allyl chloride 2-Chloropropene

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