ChemicalBook Product Catalog Chemical Reagents Organic reagents Tosylate (R)-Glycerol 1-(p-toluenesulfonate)

(R)-Glycerol 1-(p-toluenesulfonate)

(R)-Glycerol 1-(p-toluenesulfonate) Basic information
Product Name:(R)-Glycerol 1-(p-toluenesulfonate)
Synonyms:4-methylbenzenesulfonic acid 2,3-dihydroxypropyl ester;(R)-1-Toxyloxy-2,3-propanediol;(R)-1-TOSYLOXY-2,3-PROPANEDIOL (LEVODROPROPIZINE INTERMEDIATE);(R)-1,2,3-Propanetriol 4-Methylbenzenesulfonate;(R)-1-Tosyloxyglycerol;(R)-3-(p-Toluenesulfonyloxy)-1,2-propanediol;(R)-2,3-Dihydroxypropyl 4-methylbenzenesulfonate;(R)-GLYCEROL 1-(P-TOLUENESULFONATE)
CAS:41274-09-3
MF:C10H14O5S
MW:246.28
EINECS:
Product Categories:chiral;Chiral Reagents;Aromatics;Sulfur & Selenium Compounds
Mol File:41274-09-3.mol
(R)-Glycerol 1-(p-toluenesulfonate) Structure
(R)-Glycerol 1-(p-toluenesulfonate) Chemical Properties
Melting point 54-59°C
Boiling point 463.0±40.0 °C(Predicted)
density 1.351±0.06 g/cm3(Predicted)
storage temp. −20°C
solubility Dichloromethane; Chloroform; Methanol; DMF;
pka13.01±0.20(Predicted)
form Solid
color White
CAS DataBase Reference41274-09-3(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
(R)-Glycerol 1-(p-toluenesulfonate) Usage And Synthesis
UsesA chiral synthon for general asymmetric synthesis. An intermediate for the synthesis of chiral aryloxypropanolamines, which make up the majority of known potent beta-adrenergic blockers.
(R)-Glycerol 1-(p-toluenesulfonate) Preparation Products And Raw materials
Preparation ProductsCis -Tosylate
(R)-(-)-1-BENZYLOXY-3-(P-TOSYLOXY)-2-PROPANOL Sodium p-toluenesulfonate 1,6-Anhydro-4-O-p-toluenesulfonyl-β-D-glucopyranose Iron(III) p-toluenesulfonate p-Toluenesulfonic acid cis-[2-(2,4-Dichlorophenyl)-2-(1H-1,2,4-triazol-1-ylmethyl)-1,3-dioxolan-4-yl]methyl-p-toluenesulfonate PROPANEDIOL 2-O-TETRAHYDROPYRANYL-1,3-DI-O-P-TOLUENESULPHONYLPROPANETRIOL (R)-Glycerol 1-(p-toluenesulfonate) 1,6-ANHYDRO-2,4-DI-O-P-TOLUENESULFONYL-BETA-D-GLUCOPYRANOSE Glycerol (R)-(-)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YLMETHYL P-TOLUENESULFONATE 1,3-Propanediol AURORA KA-659 Tosufloxacin tosilate D-Glucitol,2,5-anhydro-,4,6-dibenzoate 1-(4-methylbenzenesulfonate) (-)-TRANS-1-O-TOSYL-2,3-ISOPROPYLIDENE-L-THREITOL 2'-TOSYLADENOSINE
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