Molybdenum silicide

Molybdenum silicide Basic information
Product Name:Molybdenum silicide
Synonyms:Molybdenum disiticide;Molybdenum silicide (99+% Mo);MOLYBDENUM DISILICIDE, POWDER, <2 MICRON , 99+%;Mo61%min,typically99.5%(metalsbasis);MOSI2 A MOLYBDENUM SILICIDE GRADE A - A PRODUCT OF H.C. STARCK;MOSI2 B MOLYBDENUM SILICIDE GRADE B - A PRODUCT OF H.C. STARCK;MOSI2 C MOLYBDENUM SILICIDE GRADE C - A PRODUCT OF H.C. STARCK;MOLYBDENUM SILICIDE: 99.5%, -325 MESH
CAS:12136-78-6
MF:MoSi2
MW:152.11
EINECS:235-231-8
Product Categories:Ceramics;Metal and Ceramic Science;Silicides;metal silicide
Mol File:12136-78-6.mol
Molybdenum silicide Structure
Molybdenum silicide Chemical Properties
Melting point 1930°C
density 6.31 g/mL at 25 °C(lit.)
form powder
Specific Gravity6.31
color Dark gray
Water Solubility Insoluble in acids and aqua regia, however, it is soluble in HF and HNO{3}Soluble in nitric acid and hydrofluoric acid. Insoluble in water most acids.
Exposure limitsACGIH: TWA 10 mg/m3; TWA 3 mg/m3
NIOSH: IDLH 5000 mg/m3
EPA Substance Registry SystemMolybdenum silicide (MoSi2) (12136-78-6)
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22
Safety Statements 36
WGK Germany 3
TSCA Yes
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Molybdenum silicide Usage And Synthesis
Chemical PropertiesMolybdenum silicide is dark-gray, crystalline powder. Not affected by air upto 1648°C. Not attacked by most inorganic acidsincluding aqua regia, but very soluble in hydrofluo-ric and nitric acids. Has high stress-rupture strength.
UsesMOLYBDENUM SILICIDE can be considered as an electrically conducting ceramic with primary use in heating elements operating at temperatures above 1,500℃ in air. It is also considered as a material for very high temperature structural applications.
UsesIn electrical resistors, in protective coatings at high temperatures, and in engine parts in space vehicles Molybdenum silicide is used in electric furnaces, glass, steel, electronics and ceramics industries. It finds application in heat treatment materials. It is also used in microelectronics as a contact material. Further, it serves as a dry lubricant.
ApplicationMolybdenum disilicide (MoSi2) is a ceramic material with excellent high-temperature oxidation resistance and corrosion resistance. It can be used as a substrate material in the fabrication of thermophotovoltaics. MoSi2 can also be used as a protective coating on carbon-carbon composites for potential applications in aerospace and thermonuclear fusion.
PreparationMolybdenum disilicide is a promising candidate material for high temperature structural applications. Molybdenum silicide is produced in much the same way as ferromolybdenum. A typical mix for the production of molybdenum silicide is 1,000pounds of molybdenum in oxide, 259 pounds of aluminum, 760 pounds of 90-percent ferrosilicon, 166 pounds of 50-percent ferro-silicon, 160 pounds of lime, and 50 pounds of high-grade fluorspar.
DefinitionMOLYBDENUM SILICIDE is A cermet.
General DescriptionThis product has been enhanced for energy efficiency.
HazardMOLYBDENUM SILICIDE is Toxic material.
Flammability and ExplosibilityNotclassified
Industrial usesHigh-temperature silicides are a new class of materials with potential applications in the temperature range 1200 to 1600 C.The silicide that seems most promising is molybdenum disilicide (MoSi2) because of its high melting temperature (2200 C) and excellent oxidation resistance. It has a tetragonal crystal structure. A major problem is its absence of ductility at temperatures up to 1000 C. It also has poor high-temperature strength due to the presence of a grain boundary silicon-rich phase that may become viscous at very high temperatures. Recent research has shown that this problem may be solved by the addition of carbon to the material.
Molybdenum silicide Preparation Products And Raw materials
HAFNIUM CARBIDE MANGANESE SILICIDE Molybdenum carbide Silicon carbide MAGNESIUM SILICIDE Vanadium carbides Boron carbide Vanadium(V) oxide Indium(III) oxide Silicon nitride Zirconium boride-Molybdenum silicide, 90:10 wt %, 99% (metals basis) Molybdenum silicide Molybdenum silicide (MoSi2), solid soln. with zirconium boride (ZrB2) MOLYBDENUM SILICIDE, 99.5% (METALS BASIS),MOLYBDENUM SILICIDE MOLYBDENUM SILICIDE SPUTTERING TARGET, 76.2MM (3.0IN) DIA X 6.35MM (0.250IN) THICK, 99.5% (METALS BASIS) ZIRCONIUM BORIDE-MOLYBDENUM SILICIDE MOLYBDENUM SILICIDE SPUTTERING TARGET, 76.2MM (3.0IN) DIA X 3.18MM (0.125IN) THICK, 99.5% (METALS BASIS) Molybdenum

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