(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97%

(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97% Basic information
Reaction
Product Name:(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97%
Synonyms:(S)-()-7,7′-Bis[di(4-methylphenyl)phosphino]-2,2′,3,3′-tetrahydro-1,1′-spirobiindene;(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97%;1,1'-[(1S)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDENE]-7,7'-DIYL]BIS[1,1-BIS(4-METHYLPHENYL)PHOSPHINE];Phosphine, 1,1'-[(1S)-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl]bis[1,1-bis(4-methylphenyl)-
CAS:817176-80-0
MF:C45H42P2
MW:644.76
EINECS:
Product Categories:
Mol File:817176-80-0.mol
(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97% Structure
(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97% Chemical Properties
Melting point 150-152°C
Boiling point 722.0±60.0 °C(Predicted)
alpha -221° (c 0.54, CH2Cl2)
storage temp. -20°C
form solid
color white
optical activity[α]22/D 206°, c = 1 in chloroform
Sensitive air sensitive
InChIKeyVLIOMJFCGWZUON-UHFFFAOYSA-N
Safety Information
WGK Germany 3
MSDS Information
(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97% Usage And Synthesis
Reaction
  1. Ligands used for the ruthenium-catalyzed hydrogenation of simple and cyclic ketones with high activity and enantioselectivity.
  2. Ligands used for palladium-catalyzed asymmetric allylic alkylations. 

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