ChemicalBook Product Catalog Organic Chemistry Hydrocarbons and derivatives Cyclic hydrocarbons 1,3-CYCLOOCTADIENE

1,3-CYCLOOCTADIENE

1,3-CYCLOOCTADIENE Basic information
Product Name:1,3-CYCLOOCTADIENE
Synonyms:1,3-CYCLOOCTADIENE;CIS, CIS-1,3-CYCLOOCTADIENE;CYCLOOCTADIENE-1,3;1,3-Cyclooctadiene, (Z,Z)-;CIS CIS-1 3-CYCLOOCTADIENE 95%;(1Z,3Z)-1,3-Cyclooctadiene;1,3-COD
CAS:3806-59-5
MF:C8H12
MW:108.18
EINECS:628-078-7
Product Categories:Alkenes;Cyclic;Organic Building Blocks
Mol File:3806-59-5.mol
1,3-CYCLOOCTADIENE Structure
1,3-CYCLOOCTADIENE Chemical Properties
Melting point −53-−51 °C(lit.)
Boiling point 55 °C34 mm Hg(lit.)
density 0.873 g/mL at 20 °C(lit.)
refractive index n20/D 1.494
Fp 76 °F
storage temp. 2-8°C
BRN 1901033
CAS DataBase Reference3806-59-5(CAS DataBase Reference)
Safety Information
Hazard Codes T
Risk Statements 10-36/38-65-36/37/38-25
Safety Statements 26-45
RIDADR UN 2520 3/PG 3
WGK Germany 3
HazardClass 3
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
1,3-CYCLOOCTADIENE Usage And Synthesis
Uses1,3-Cyclooctadiene is a reagent used in the synthesis of catalytically active membranelike devices.
Synthesis Reference(s)Journal of the American Chemical Society, 83, p. 2954, 1961 DOI: 10.1021/ja01474a039
General DescriptionThe photosensitized cyclization of cis,cis-1,3-cyclooctadiene to bicyclo[4.2.0]oct-7-ene was studied. It proceeded by first isomerization of the diene to its cis, trans isomer followed by cyclization.
1,3-CYCLOOCTADIENE Preparation Products And Raw materials
1,5-Dimethyl cyclooctadiene,5-Cyclooctadiene,1,5-dimethyl- 3-DI-I-PROPYLPHOSPHINO-2-(N,N-DIMETHYLAMINO)-1H-INDENE(1,5-CYCLOOCTADIENE)IRIDIUM(I) HEXAFLUOROPHOSPHATE, MIN. 98 (1Z,5Z)-cyclooctadien (R)-(-)-4,12-BIS(DI-3,5-XYLYLPHOSPHINO)[2.2]PARACYCLOPHANE(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE 9-Phosphabicyclononane BIS(ACETONITRILE)(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE (+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TRIFLUOROMETHANESULFONATE 1 5-CYCLOOCTADIENE-KUPFER(I)-CHLORID (1 5-CYCLOOCTADIENE)(1 3 5-CYCLOOCTATRI& (S,S,S,S)-2,3-BIS(2,5-DIMETHYL-PHOSPHOLANYL)BENZO[B]THIOPHENE CYCLOOCTADIENE RHO (+)-2,3-BIS((2R,5R)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZO[B]THIOPHENE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Dichloro(cycloocta-1,5-diene)ruthenium(II) dichloro[(1,2,5,6-eta)-1,5-cyclooctadiene]-palladi 3-DI-I-PROPYLPHOSPHORANYLIDENE-2-(N,N-DIMETHYLAMINO)-1H-INDENE(1,5-CYCLOOCTADIENE)RHODIUM(I) (METHYLCYCLOPENTADIENYL)(1,5-CYCLOOCTADIENE)IRIDIUM(I) (-)-1,1'-BIS((2S,4S)-2,4-DIETHYLPHOSPHOTANO)FERROCENE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE, MIN BIS(METHALLYL)(1,5-CYCLOOCTADIENE)RUTHENIUM BIS-(1,5-CYCLOOCTADIENE)RHODIUM-I)
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