IODOMETHYL-TRIPHENYL-PHOSPHONIUM IODIDE

IODOMETHYL-TRIPHENYL-PHOSPHONIUM IODIDE Basic information

Product Name:	IODOMETHYL-TRIPHENYL-PHOSPHONIUM IODIDE
Synonyms:	iodo-(iodomethyl)-triphenylphosphorane;Iodomethyl triphenylphosphonium iodide 95 %;NSC 116665;(Iodomethyl)triphenylphosphonium iodide 95%;iodomethyl(triphenyl)phosphanium,iodide;iodomethyl-triphenyl-phosphanium;IodomethyL;-phosphonium iodide
CAS:	3020-28-8
MF:	C19H17I2P
MW:	530.13
EINECS:
Product Categories:
Mol File:	3020-28-8.mol

IODOMETHYL-TRIPHENYL-PHOSPHONIUM IODIDE Chemical Properties

Melting point	260-266°C
storage temp.	under inert gas (nitrogen or Argon) at 2–8 °C

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-28

MSDS Information

IODOMETHYL-TRIPHENYL-PHOSPHONIUM IODIDE Usage And Synthesis

Uses

Reactant or reagent for synthesis of:

Phosphacyclic compounds via oxidative dimerizations
Enamides via cross-coupling
Cyclopeptide alkaloids for use as antibacterial or cytotoxic agents
Terminal alkynes via dehydrohalogenation of aldehydes

Reactant for vinylcyclopropanation / cyclopentenation of strained alkenes using a sequential carborhodation process

Used as an olefination agent in the Lewis acid catalysis of electrocyclization of trienes

IODOMETHYL-TRIPHENYL-PHOSPHONIUM IODIDE Preparation Products And Raw materials

Preparation Products

Cyclohexene, 2-ethenyl-1,3,3-trimethyl-

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IODOMETHYL-TRIPHENYL-PHOSPHONIUM IODIDE

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