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| | 1-ACENAPHTHENOL Basic information |
| Product Name: | 1-ACENAPHTHENOL | | Synonyms: | 1-Acenaphthenol (Acenaphthene-1-hydroxy);1-Acenaphthylenol, 1,2-dihydro- (9CI);A406_ALDRICH;Acenaphthene-1-ol;EINECS 228-618-8;NSC 22834;NSC22834;28807-94-5 | | CAS: | 6306-07-6 | | MF: | C12H10O | | MW: | 170.21 | | EINECS: | 228-618-8 | | Product Categories: | Aromatic Phenols | | Mol File: | 6306-07-6.mol |  |
| | 1-ACENAPHTHENOL Chemical Properties |
| Melting point | 145-148 °C (lit.) | | Boiling point | 369℃ | | density | 1.290 | | Fp | 129℃ | | storage temp. | -20°C Freezer | | solubility | Chloroform (Slightly, Sonicated), Methanol (Slightly) | | pka | 13.68±0.20(Predicted) | | form | Solid | | color | Yellow to Dark Yellow | | BRN | 2048222 | | Stability: | Stable. Combustible. Incompatible with strong oxidizing agents. | | CAS DataBase Reference | 6306-07-6(CAS DataBase Reference) |
| WGK Germany | 3 | | HS Code | 2906.29.6000 | | HazardClass | IRRITANT |
| | 1-ACENAPHTHENOL Usage And Synthesis |
| Description | 1-Acenaphthenol is a white to cream solid in appearance. It is almost insoluble in water.
1-Acenaphthenol is a stable and combustible chemical substance. It is incompatible with
strong oxidising agents. It is used in the syntheses of organic compounds.
Exposures to 1-acenaphthenol cause irritant effects. It is harmful by ingestion, inhalation,
as well as through skin absorption. There are no complete data on the toxicology of
1-acenaphthenol. | | Chemical Properties | 1-Acenaphthenol is a white to cream solid in appearance. It is almost insoluble in water.
1-Acenaphthenol is a stable and combustible chemical substance. It is incompatible with
strong oxidizing agents. It is used in the syntheses of organic compounds. | | Uses | 1-Acenaphthenol is a product of the microbial metabolism and photolysis of acenaphthene, of acenaphthene, a polycyclic hydrocarbon that has potential to act as polyploidizing agents in plants. 1-Acenaphthenol is also a known substrate of dihydrodiol dehydrogenases. | | Health Hazard | Exposures to 1-acenaphthenol cause irritant effects. It is harmful by ingestion, inhalation,
or skin absorption. There are no complete data on the toxicology of 1-acenaphthenol. | | Purification Methods | If highly coloured (yellow), dissolve it in boiling *benzene (14g in 200mL), add charcoal (0.5g), filter it through a heated funnel, concentrate to 100mL and cool to give almost colourless needles. *Benzene vapour is TOXIC; use an efficient fume cupboard. The acetate has b 166-168o/5mm (bath temperature 180-185o). [Cason Org Synth Coll Vol III 3 1955.] It can also be recrystallised from *C6H6 or EtOH [Fieser & Cason J Am Chem Soc 62 432 1940]. It forms a brick-red crystalline complex with 2,4,5,7-tetranitrofluoren-9-one which is recrystallised from AcOH and is dried in a vacuum over KOH and P2O5 at room temperature, m 170-172o [Newman & Lutz J Am Chem Soc 78 2469 1956]. [Beilstein 6 IV 4623.] |
| | 1-ACENAPHTHENOL Preparation Products And Raw materials |
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