[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)

[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Basic information
Product Name:[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)
Synonyms:Ni(dppf)Cl2;DPPF·NICL2;1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE NICKEL DICHLORIDE;[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]NICKEL(II) DICHLORIDE;[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLORONICKEL(II);DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]NICKEL(II);(1,1'-bis(diphenylphosphino)ferrocene)-dichloroni;[1, 1’-Bis(diphenyphosphino)ferrocene]dichloronickel(II)
CAS:67292-34-6
MF:C34H22Cl2FeNiP2
MW:677.94
EINECS:
Product Categories:Ni;Catalysts for Organic Synthesis;Classes of Metal Compounds;Fe (Iron) Compounds;Ferrocenes;Homogeneous Catalysts;pharmacetical;Metal Complexes;Metallocenes;Ni (Nickel) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;Catalysis and Inorganic Chemistry;Chemical Synthesis;Metal Compounds
Mol File:67292-34-6.mol
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Structure
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Chemical Properties
Melting point 285 °C (dec.)(lit.)
storage temp. Inert atmosphere,Room Temperature
form crystal
color green micro
Water Solubility Insoluble in water.
Exposure limitsNIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
Safety Information
Hazard Codes T
Risk Statements 45-42/43
Safety Statements 53-22-36/37/39-45
RIDADR 2811
WGK Germany 3
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Usage And Synthesis
Chemical PropertiesYellow powder
Usesdiphosphine 1,1'-bis(diphenylphosphino)ferrocene (dppf) are used in transition metal-catalyzed reactions to synthesize pharmaceuticals and agrochemicals.
Uses(1,1''-Bis(diphenylphosphino)ferrocene)dichloronickel(II) is an organometallic catalyst used in a variety of synthetic applications, such as the gem-?difluoropropargylation of alkylzinc reagents, or cross coupling reactions to form 2,?3,?5,?6-?tetrasubstituted dehydropiperidines.
Usessuzuki reaction
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Preparation Products And Raw materials
Raw materialsEthanol-->Dichloromethane-->Nickel(II) chloride hexahydrate-->1,1'-Bis(diphenylphosphino)ferrocene
1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, Silane,[1,1'-biphenyl]-3-yltrimethyl- [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Nickel chloride Diphenylphosphine Ferrocene [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) 1,1'-Bis(diphenylphosphino)ferrocene ALLYL(CYCLOPENTADIENYL)NICKEL(II) 97 DICHLOROBIS(TRIMETHYLPHOSPHINE)NICKEL(II) Chlorodiphenylphosphine N-(Carboxymethyl)-N-(phosphonomethyl)-glycine Nickel Iron (80:20wt%) in cone shaped (refer to drawing) Nickel chloride NICKELOCENE

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