3-ETHOXY-2-CYCLOHEXEN-1-ONE

3-ETHOXY-2-CYCLOHEXEN-1-ONE Basic information

Product Name:	3-ETHOXY-2-CYCLOHEXEN-1-ONE
Synonyms:	3-ETHOXY-2-CYCLOHEXEN-1-ONE;3-ETHOXY-2-CYCLOHEXENE-1-ONE;2-Cyclohexen-1-one, 3-ethoxy-;2-Cyclohexen-1-one,3-ethoxy-;3-Ethoxy-2-cyclohexenone;3-ethoxycyclohex-2-en-1-one;3-ethoxycyclohex-2-ene-1-one;3-Ethoxy-cyclohex-2-enone
CAS:	5323-87-5
MF:	C8H12O2
MW:	140.18
EINECS:	226-190-7
Product Categories:	Ketones;C7 to C8;Carbonyl Compounds
Mol File:	5323-87-5.mol

3-ETHOXY-2-CYCLOHEXEN-1-ONE Chemical Properties

Boiling point	76-78 °C/1 mmHg (lit.)
density	0.963 g/mL at 25 °C (lit.)
refractive index	1.503-1.505
Fp	107 °C
storage temp.	2-8°C
form	Crystalline Powder
color	Off-white to peach
Water Solubility	Slightly soluble in water.
BRN	2042049
LogP	0.489 (est)
CAS DataBase Reference	5323-87-5(CAS DataBase Reference)

Safety Information

Safety Statements	24/25
WGK Germany	3
HS Code	29145000

MSDS Information

Provider	Language
ACROS	English
ALFA	English

3-ETHOXY-2-CYCLOHEXEN-1-ONE Usage And Synthesis

Chemical Properties	Clear colorless to pale yellow liquid
Uses	3-Ethoxy-2-cyclohexen-1-one is a useful intermediate for the preparation of 3-alkyl- or aryl-2-cyclohexen-1-ones, by addition of organometallic reagents and subsequent hydrolysis. It helps in kinetic enolate formation (LDA) and alkylation occurs at the 6-position, the Stork-Danheiser kinetic alkylation procedure, which has found extensive use in alicyclic synthesis.

3-ETHOXY-2-CYCLOHEXEN-1-ONE Preparation Products And Raw materials

Raw materials	2-Cyclohexen-1-one, 3-propoxy--->5-Hexynoyl chloride-->1,3-DIETHOXYBENZENE-->3-METHOXY-2-CYCLOHEXEN-1-ONE-->DICHLOROETHOXYOXOVANADIUM (V)-->3-BUTOXYCYCLOHEX-2-EN-1-ONE-->5-HEXYNOIC ACID-->Sodium ethoxide-->Ethanol-->Triethyl orthoformate-->1,3-Cyclohexanedione
Preparation Products	3-CHLOROCYCLOHEX-2-ENONE

5,5-DIMETHYL-3-OXO-1-CYCLOHEXENYL 4-CHLOROBENZENECARBOXYLATE SALOR-INT L147834-1EA 7,7-DIMETHYL-4-PHENYL-4,6,7,8-TETRAHYDRO-2H-CHROMENE-2,5(3H)-DIONE 3-CHLORO-N-(2,5-DIOXO-5,6,7,8-TETRAHYDRO-2H-CHROMEN-3-YL)BENZENECARBOXAMIDE AKOS BBS-00008203 N-(2,5-DIOXO-5,6,7,8-TETRAHYDRO-2H-CHROMEN-3-YL)-4-METHOXYBENZENECARBOXAMIDE SALOR-INT L140902-1EA N-(2,5-DIOXO-5,6,7,8-TETRAHYDRO-2H-CHROMEN-3-YL)BENZENECARBOXAMIDE 3-ISOBUTOXY-2-CYCLOHEXEN-1-ONE 4-(4-METHOXYPHENYL)-7,7-DIMETHYL-4,6,7,8-TETRAHYDRO-2H-CHROMENE-2,5(3H)-DIONE N-(2,5-DIOXO-5,6,7,8-TETRAHYDRO-2H-CHROMEN-3-YL)-4-METHYLBENZENECARBOXAMIDE 9-(2-HYDROXY-4,4-DIMETHYL-6-OXOCYCLOHEX-1-ENYL)-3,3,6,6-TETRAMETHYL-3,4,6,7-TETRAHYDRO-2H-XANTHENE-1,8(5H,9H)-DIONE 4-CHLORO-N-(2,5-DIOXO-5,6,7,8-TETRAHYDRO-2H-CHROMEN-3-YL)BENZENECARBOXAMIDE SALOR-INT L140929-1EA SALOR-INT L133965-1EA 3-OXO-1-CYCLOHEXENYL 1-[3-CHLORO-5-(TRIFLUOROMETHYL)-2-PYRIDINYL]-1H-PYRROLE-2-CARBOXYLATE 3-BUTOXYCYCLOHEX-2-EN-1-ONE 4-[4-(DIMETHYLAMINO)PHENYL]-7,7-DIMETHYL-4,6,7,8-TETRAHYDRO-2H-CHROMENE-2,5(3H)-DIONE

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