ChemicalBook Product Catalog Chemical Reagents Organic reagents Phosphine ligand (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE Basic information
Reaction
Product Name:(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE
Synonyms:MANDYPHOS SL-M002-1;(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE;(R,R)-1,1'-BIS[(R)-ALPHA-(DIMETHYLA;(S,S)-(+)-2,2'-BIS[(R)-(N,N-DIMETHYLAMINO)(PHENYL)METHYL]-1,1'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE;(R,R)-1,1'-BIS[(R)-ALPHA-(DIMETHYLAMINO)PHENYLMETHYL]-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE;(R,R)-1,1#-Bis[-(dimethylamino)benzyl]-(S,S)-2,2#-bis(dicyc;(S,S)-(+)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(dicyclohexylphosphino)ferrocene,min.97%;(r,r)-1,1'-bis[(r)-α-(dimethylamino)phenylmethyl]-2,2'-bis(dicyclohexylphosphino)ferrocene (acc to cas)
CAS:494227-35-9
MF:C52H72FeN2P2
MW:842.95
EINECS:
Product Categories:Chiral Phosphine;Ferrocene Series;Mandyphos Series
Mol File:494227-35-9.mol
(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE Structure
(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE Chemical Properties
alpha +54.6° (c 1.0, CHCl3)
form solid
color orange-red
Stability:store cold
CAS DataBase Reference494227-35-9
Safety Information
WGK Germany 3
HS Code 29319090
MSDS Information
(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE Usage And Synthesis
ReactionLigand for a copper-catalyzed domino conjugated reduction/aldol reaction of methyl acrylate with various alkyl aryl ketones. Reactions of 494227-35-9_1 Ligand for gold catalyzed Phenol synthesis from furyldialkyne Reactions of 494227-35-9_2
Ligand for asymmetric palladium-catalyzed cross-coupling of aryl triflates with [(η6-benzylamine)Cr(CO)3] Reactions of 494227-35-9_3
Chemical PropertiesOrange powder
General Descriptionsold in collaboration with Solvias AG
(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE Preparation Products And Raw materials
(S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DIPHENYLPHOSPHINO)FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE Ferrocene 1,1'-DIETHYLFERROCENE N,N-Dimethylaminomethylferrocene (+/-)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE (R)-(+)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE 1,1'-DIMETHYLFERROCENE 1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE 1,1'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE
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