NESSLER'S REAGENT

NESSLER'S REAGENT Basic information
Product Name:NESSLER'S REAGENT
Synonyms:NESSLER'S REAGENT SOLUTION;AMMONIA NITROGEN 2;MAYER'S REAGENT;MERCURY(II) POTASSIUM IODIDE;MERCURIC POTASSIUM IODIDE;MERCURIC-POTASSIUM IODIDE TS;MERCURIC-POTASSIUM IODIDE TS, ALKALINE;Mercury potassium iodide
CAS:7783-33-7
MF:HgI4K2
MW:786.4
EINECS:231-990-4
Product Categories:Inorganics
Mol File:7783-33-7.mol
NESSLER'S REAGENT Structure
NESSLER'S REAGENT Chemical Properties
Melting point 120-127 °C(lit.)
Boiling point 105°C
density 1.16 g/mL at 20 °C
Fp >230 °F
form Liquid
Specific Gravity1.097
color Yellow to orange
OdorOdorless
Water Solubility Soluble in water.
Sensitive Hygroscopic
Merck 13,7773
Exposure limitsACGIH: TWA 0.025 mg/m3 (Skin)
NIOSH: IDLH 10 mg/m3; TWA 0.05 mg/m3; Ceiling 0.1 mg/m3
Stability:Stable, but light sensitive. Incompatible with strong oxidizing agents.
InChIKeyOPCMAZHMYZRPID-UHFFFAOYSA-J
EPA Substance Registry SystemPotassium mercuric iodide (7783-33-7)
Safety Information
Hazard Codes T,N,T+
Risk Statements 26/27/28-33-35-51/53-52/53-23/24/25-48/21/22-25-50/53-68-24/25
Safety Statements 45-36/37-61-36/37/39-28-26-60-13
RIDADR UN 3287 6.1/PG 3
WGK Germany 3
RTECS OU9670000
8-30
TSCA Yes
HazardClass 6.1
PackingGroup II
HS Code 28521000
Hazardous Substances Data7783-33-7(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
NESSLER'S REAGENT Usage And Synthesis
Chemical Propertieslight yellow liquid
UsesMercury(II) potassium iodide is used as a pharmaceutical intermediate. It is also used as reagents, chemical research and organic intermediates.
UsesDetecting the presence of ammonia, particularly in very small amounts.
DefinitionSolution of mercuric iodide in potassium iodide.
General DescriptionOdorless yellow crystals. Crystallizes with either one, two or three molecules of water. Soluble in water and denser than water. Commercially available in the anhydrous form. Highly toxic by ingestion, inhalation, and skin absorption.
Air & Water ReactionsDeliquescent. Very water soluble.
Reactivity ProfileMERCURIC POTASSIUM IODIDE is incompatible with acetylene, ammonia, chlorine dioxide, azides, calcium (amalgam formation), sodium carbide, lithium, rubidium, copper . NESSLER'S REAGENT behave in aqueous solution as a weak acid.
HazardHighly toxic by ingestion, inhalation, and skin absorption.
Health HazardHighly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire HazardNon-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Containers may explode when heated. Runoff may pollute waterways.
Safety ProfileA poison. Moderately toxic by skin contact and intraperitoneal routes. When heated to decomposition it emits very toxic fumes of Hg, K2O, and I-. See also MERCURY.
NESSLER'S REAGENT Preparation Products And Raw materials
Raw materialsNitric acid-->Potassium iodide-->Mercury
Aluminon Ammonium phosphate dibasic NESSLER'S REAGENT BISMUTH POTASSIUM IODIDE Lucas Zinc hydroxide Potassium dichromate Sodium iodide Nessler Bismuth nitrate oxide MERCURY(II) SULFATE COBALT THIOCYANATE Mercury chloride Nitrogen MERCURY(II) IODIDE NESSLER'S REAGENT Iodine Mercury

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