ChemicalBook Product Catalog Inorganic chemistry Inorganic salts Metal halide and Halogen salt Metal iodide and salt NICKEL IODIDE

NICKEL IODIDE

NICKEL IODIDE Basic information
Product Name:NICKEL IODIDE
Synonyms:NICKEL IODIDE;NICKEL IODIDE (OUS);nickel(2+)iodide;nickeldiiodide;nickeliodide(nii2);nickeliodide(nii2)[qr];nickelousiodide;Nickel(II) iodide anhydrous, powder, 99.99% trace metals basis
CAS:13462-90-3
MF:I2Ni
MW:312.5
EINECS:236-666-6
Product Categories:Crystal Grade Inorganics;Materials Science;Metal and Ceramic Science;Nickel;Nickel Salts;Catalysis and Inorganic Chemistry;Chemical Synthesis;Catalysis and Inorganic Chemistry;Chemical Synthesis;Crystal Grade Inorganics;Metal and Ceramic Science;Nickel Salts;NickelMetal and Ceramic Science;Salts;metal halide
Mol File:13462-90-3.mol
NICKEL IODIDE Structure
NICKEL IODIDE Chemical Properties
Melting point 797 °C(lit.)
Boiling point sublimes [LID94]
density 5.83 g/mL at 25 °C(lit.)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility H2O: slightly soluble(lit.)
form Powder
Specific Gravity5.834
color black
Water Solubility Soluble in water and alcohols.
Sensitive Hygroscopic
Merck 13,6535
Exposure limitsACGIH: TWA 0.1 mg/m3
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
Stability:hygroscopic
CAS DataBase Reference13462-90-3(CAS DataBase Reference)
EPA Substance Registry SystemNickel iodide (NiI2) (13462-90-3)
Safety Information
Hazard Codes T
Risk Statements 45-61-42/43
Safety Statements 53-22-26-36/37/39-45
RIDADR UN 3260 8/PG 2
WGK Germany 3
TSCA Yes
HazardClass 6.1(b)
PackingGroup III
HS Code 2827600090
Hazardous Substances Data13462-90-3(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
NICKEL IODIDE Usage And Synthesis
Chemical PropertiesBlack, crystalline powder or blue-green crystals; hygroscopic.Soluble in alcohol and water.
UsesNickel Diiodide is used in preparation of Nickel complexes for migratory reductive cross-coupling.
UsesStrongly accelerates Sml2 mediated homocoupling of imines into vicinal diamines and heterocoupling reactions between imines and ketones.1
UsesStrongly accelerates Sml2 mediated homocoupling of imines into vicinal diamines and heterocoupling reactions between imines and ketones.
PreparationNickel iodide can be prepared by dehydration of the hexahydrate or by the metathetic reaction between sodium iodide and nickel(II) chloride or nitrate in ethanol. It has the CdCl2 type lattice and is paramagnetic down to 75°K. Only one hydrate is well characterized—the blue-green NiI2?6H20 ; unlike the other halide hexahydrates, this contains [Ni(H2O)6]2+ cations.
HazardToxic by ingestion.
NICKEL IODIDE Preparation Products And Raw materials
NICKEL SULFIDE Zinc sulfide Cuprous iodide Nickel carbonate NICKEL BROMATE Cadmium iodide IRON (II) IODIDE Cuprous iodide MANGANESE(II) IODIDE NICKEL OXALATE DIHYDRATE Iodine Nickel sulfate COBALT(II) IODIDE NICKEL IODIDE Nickel HEXAAMINENICKEL(II) IODIDE BIS(TRIPHENYLPHOSPHINE)NICKEL(II) IODIDE Nickel(II) iodide hexahydrate
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