2-Benzylaminopyridine

2-Benzylaminopyridine Basic information

Product Name:	2-Benzylaminopyridine
Synonyms:	BENZYL-PYRIDIN-2-YL-AMINE;AURORA KA-4160;ALPHA-BENZYLAMINOPYRIDINE;n-(phenylmethyl)-2-pyridinamin;N-(2-Pyridine)benzylamine;N-Benzyl-2-pyridinamine;N-Benzyl-2-pyridylamine~N-(2-Pyridyl)benzylamine;2-BENZYLAMINOPYRIDINE
CAS:	6935-27-9
MF:	C12H12N2
MW:	184.24
EINECS:	230-060-5
Product Categories:	Pyridines derivates;C9 to C46;Heterocyclic Building Blocks;Pyridines
Mol File:	6935-27-9.mol

2-Benzylaminopyridine Chemical Properties

Melting point	95-97 °C (lit.)
Boiling point	116-131 °C/0.6 mmHg (lit.)
density	1.1160 (rough estimate)
refractive index	1.6266 (estimate)
Fp	182°C/12mm
storage temp.	Sealed in dry,2-8°C
form	powder to crystal
pka	6.61±0.10(Predicted)
color	White to Light yellow to Light orange
BRN	134309
CAS DataBase Reference	6935-27-9(CAS DataBase Reference)
EPA Substance Registry System	2-Pyridinamine, N-(phenylmethyl)- (6935-27-9)

Safety Information

Hazard Codes	Xn,Xi
Risk Statements	22-37/38-41-40-36/37/38-20/21/22
Safety Statements	26-39-36-22
WGK Germany	3
RTECS	US2700000
TSCA	Yes
HS Code	29333999

MSDS Information

Provider	Language
2-Benzylaminopyridine	English
SigmaAldrich	English
ACROS	English
ALFA	English

2-Benzylaminopyridine Usage And Synthesis

Chemical Properties	white to off-white powder
Uses	2-(Benzylamino)pyridine is used as a reactant in the amination of aryl chlorides, bromides, and triflates catalyzed by palladium complexes.
Synthesis Reference(s)	Organic Syntheses, Coll. Vol. 4, p. 91, 1963 The Journal of Organic Chemistry, 67, p. 4965, 2002 DOI: 10.1021/jo020057z
General Description	2-Benzylaminopyridine on reaction with BBr₃ yields the corresponding amino or hydroxy substituted compounds. It forms 5- and 6-coordinated organometallic complexes of gallium(III) and indium(III).

2-Benzylaminopyridine Preparation Products And Raw materials

Raw materials

Potassium hydroxide-->2-Aminopyridine-->Benzenecarboximidamide, N-2-pyridinyl--->(4-CHLORO-BENZYL)-PYRIDIN-2-YL-AMINE DIHYDROCHLORIDE-->2-Nitropyridine-->2-Iodopyridine-->Benzaldehyde-->Benzamide-->4-Chlorobenzyl alcohol-->2-Bromopyridine-->2-Chloropyridine-->Pyridine-N-oxide-->Benzyl alcohol-->Benzyl bromide-->Benzylamine

Benzyl butyrate Benzoyl peroxide CHEMBRDG-BB 9071156 Benzyl chloride 2-Benzylaminopyridine TRIPELENNAMINE CITRATE 2-Aminobenzylchloride 4-Methylpyridine DIMETHYLAMINOPYRIDINE, POLYMER-BOUND 3-Aminopyridine 2-(4-Methoxybenzylamino)pyridine 2,6-Lutidine Benzyl 2-Aminopyridine Tris(hydroxymethyl)aminomethane Benzyl acetate Benzyl benzoate 4-Dimethylaminopyridine

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