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Methyl 2-methoxybenzoate

Methyl 2-methoxybenzoate Basic information
Product Name:Methyl 2-methoxybenzoate
Synonyms:RARECHEM AL BF 0022;O-ANISIC ACID METHYL ESTER;dimethylsalicylate;Methyl ester of o-Methoxybenzoic acid;Methylsalicylate methyl ether;methylsalicylatemethylether;Methylsalicylateo-methylether;o-Methoxy methyl benzoate
CAS:606-45-1
MF:C9H10O3
MW:166.17
EINECS:210-118-6
Product Categories:Aromatic Esters
Mol File:606-45-1.mol
Methyl 2-methoxybenzoate Structure
Methyl 2-methoxybenzoate Chemical Properties
Boiling point 248 °C (lit.)
density 1.157 g/mL at 25 °C (lit.)
FEMA 2717 | METHYL O-METHOXYBENZOATE
refractive index n20/D 1.534(lit.)
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
form clear liquid
color Colorless to Almost colorless
Specific Gravity1.16
Odorat 100.00 %. herbal floral hyacinth cananga fruity blackcurrant
Odor Typeherbal
JECFA Number880
BRN 2207356
InChIKeyPFYHAAAQPNMZHO-UHFFFAOYSA-N
LogP2.04
CAS DataBase Reference606-45-1(CAS DataBase Reference)
NIST Chemistry ReferenceBenzoic acid, 2-methoxy-, methyl ester(606-45-1)
EPA Substance Registry SystemBenzoic acid, 2-methoxy-, methyl ester (606-45-1)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-37/39
WGK Germany 2
RTECS DH3549000
TSCA Yes
HS Code 29189090
MSDS Information
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Methyl 2-methoxybenzoate English
ACROS English
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Methyl 2-methoxybenzoate Usage And Synthesis
DescriptionMETHYL ο-METHOXYBENZOATE has a herbaceous, anise-like odor with a sweet taste reminiscent of melon. May be prepared by esterification of anisic acid with methanol; or from sodium anisate and dimethylsulfate in the presence of methanol.
Chemical PropertiesMethyl o-methoxybenzoate has an herbaceous, warm, anise-like odor and a sweet taste reminiscent of melon
Chemical Propertiesclear colorless to slightly yellow liquid
OccurrenceReported found in a grape and mushroom variety, Trametes graveolens, Vitis labrusca L. and black tea.
UsesMethyl 2-methoxybenzoate has been used in the synthesis of (+/?)-vibralactone.
PreparationBy esterification of anisic acid with methanol, or from sodium anisate and dimethylsulfate in the presence of methanol
DefinitionChEBI: Methyl 2-methoxybenzoate is a methoxybenzoic acid.
Aroma threshold valuesAroma characteristics at 1.0%: fruity, winey, fermented with a slightly musty and anisic nuance.
Taste threshold valuesTaste characteristics at 10 ppm: fruity, anisic, fermented and winey with a good mouthfeel
General DescriptionFeCl2 catalyzed cross-coupling reaction between methyl 2-methoxybenzoate and diphenylmethane under various reaction conditions has been investigated.
Methyl 2-methoxybenzoate Preparation Products And Raw materials
Preparation ProductsSalicylic acid-->ETHYL (2-METHOXYBENZOYL)ACETATE-->methyl 5-bromo-2-methoxybenzoate-->2'-HYDROXYFLAVANONE-->2-Methoxybenzyl alcohol-->1,3-bis(2-methoxyphenyl)propane-1,3-dione-->3-(2-METHOXYPHENYL)PENTAN-3-OL
o-Toluic acid o-Anisaldehyde 3,4-Dimethoxybenzoic acid Methylparaben 3,5-Dimethoxybenzoic acid Bensulfuron methyl Methyl o-toluate Anisole (Trifluoromethoxy)benzene Methyl 4-cyanobenzoate 2,3-Dimethoxybenzoic acid Thiophanate-methyl p-Anisaldehyde Methyl benzoate Anthranilic acid Methyl acetate Methyl bromide METHYL THIOPHENE-2-CARBOXYLATE
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