SHVO'S CATALYST

SHVO'S CATALYST Basic information
Reactions
Product Name:SHVO'S CATALYST
Synonyms:1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II);1-Hydroxytetraphenylcylclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-Mu-hydrotetracarbonyldirutheniuM(II);1-Hydroxytetraphenylcylclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldirutheniuM(II);1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-^M-hydrotetracarbonyldirutheniuM(II), 98%;1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldirutheniuM(II) SHVO'S CATALYST;Ruthenium,tetracarbonyl-m-hydro[(1,2,3,4,5-h)-1-hydroxylato-2,3,4,5-tetraphenyl-2,4-cyclopentadien-1-yl][(1,2,3,4,5-h)-1-hydroxy-2,3,4,5-tetraphenyl-2,4-cyclopentadien-1-yl]di-;1-Hydroxytetraphenyl-cyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-u-hydrotetracarbonyldiruthenium(II);1-HYDROXYTETRAPHENYLCYCLOPENTADIENYL(TETRAPHENYL-2,4-CYCLOPENTADIEN-1-ONE)-1-HYDROTETRACARBONYLDIRUTHENIUM(II)
CAS:104439-77-2
MF:C62H41O6Ru25*
MW:1084.13
EINECS:
Product Categories:Ru
Mol File:104439-77-2.mol
SHVO'S CATALYST Structure
SHVO'S CATALYST Chemical Properties
Melting point 223-227 °C
storage temp. Inert atmosphere,Room Temperature
solubility DMSO (Slightly)
form Powder
color orange
Water Solubility Soluble in water and polar organic solvents.
Sensitive Moisture Sensitive
Merck 14,8483
CAS DataBase Reference104439-77-2
Safety Information
Safety Statements 22-24/25
WGK Germany 3
HS Code 2843.90.0000
MSDS Information
SHVO'S CATALYST Usage And Synthesis
Reactions
  1. In conjugation with lipase, ruthenium catalyst used in the asymmetric transformation of ketones and enol acetates into chiral acetates.
  2. Dynamic kinetic resolution resulting from the ruthenium catalyzed racemization of enzymatically- resolved substrates.
  3. Conversion of secondary amines to primary amines in the presence of ammonia.
  4. Co-catalyt for aerobic lactonization of diols. 
Reactions of 104439-77-2
UsesCatalyst in organic syntheses for hydrogen transfers including disproportionation of aldehydes, reduction of ketones and aldehydes, oxidation and/or racemization of alcohols and amines.
UsesThe Shvo catalyst is an organoruthenium compound that is used for transfer hydrogenation
SHVO'S CATALYST Preparation Products And Raw materials
SHVO'S CATALYST 2,5-Dimethyl-3,4-diphenylcyclopentadienone 4-METHYL-3-PHENYLPENT-3-EN-2-ONE 1,2,3,4-TETRAPHENYL-1,3-CYCLOPENTADIENE Tetraphenylcyclopentadienone

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