ChemicalBook Product Catalog Organic Chemistry Organometallic compounds Organic palladium 1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE (1,4-NAPHTHOQUINONE)PALLADIUM(0) DIMER

1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE (1,4-NAPHTHOQUINONE)PALLADIUM(0) DIMER

1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE (1,4-NAPHTHOQUINONE)PALLADIUM(0) DIMER Basic information
Reaction
Product Name:1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE (1,4-NAPHTHOQUINONE)PALLADIUM(0) DIMER
Synonyms:BIS[1,3-DIHYDRO-1,3-(2,4,6-TRIMETHYLPHENYL)-2H-IMIDAZOL-2-YLIDENE]BIS[MU-[(2,3-ETA)-1,4-NAPHTHALENEDIONE-KAPPAO]]DI-PALLADIUM;PD(0)-NAPHTHOCHINONE-1,3-BIS(2,4,6-TRI-METHYLPHENYL)IMIDAZOL-2-YLIDENE;NAPHTHOQUINONE-1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLE-2-YLIDENEPALLADIUM(0);1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene(1,4-naphthoquinone)palladium(0)dimer,96%;bis[1,3-dihydro-1,3-(2,4,6-trimethylphenyl)-2h-imidazol-2-ylidene]bis[μ-[(2,3-η)-1,4-naphthalenedione-κo]]di-palladium;NAPHTHOQUINONE-1,3-BIS(MESITYL)IMIDAZOLE-2-YLIDENEPALLADIUM(0);1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium dimer;Umicore CX12
CAS:467220-49-1
MF:2C21H24N2Pd.2C10H6O2
MW:1138.02
EINECS:
Product Categories:Pd;organometallic complex
Mol File:467220-49-1.mol
1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE (1,4-NAPHTHOQUINONE)PALLADIUM(0) DIMER Structure
1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE (1,4-NAPHTHOQUINONE)PALLADIUM(0) DIMER Chemical Properties
Melting point >300 °C
form Powder
color orange-red
Sensitive air sensitive
CAS DataBase Reference467220-49-1
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-43
Safety Statements 26-36/37
WGK Germany 3
HS Code 28439000
MSDS Information
ProviderLanguage
SigmaAldrich English
1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE (1,4-NAPHTHOQUINONE)PALLADIUM(0) DIMER Usage And Synthesis
Reaction
  1. Catalyst for Heck reactions in ionic liquids.
  2. Catalyst for the cross-coupling of aryl diazonium salts.
  3. Catalyst for the Kumada cross-coupling of alkyl chlorides.
Reactions of 467220-49-1
Chemical PropertiesOrange crystal
UsesIt can be used as a catalyst in the Kumada cross-coupling of aryl magnesium reagents with functionalized alkyl chlorides at room temperature to form substituted alkanes.
General Description1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium(0) dimer is an N-heterocyclic carbene based palladium catalyst that shows high catalytic activity in C-C coupling reactions.
1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE (1,4-NAPHTHOQUINONE)PALLADIUM(0) DIMER Preparation Products And Raw materials
1 3-BIS(2 6-DIISOPROPYLPHENYL)IMIDAZOL-& Naphthochinone-1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazole-2-ylidenepalladium(0)-dimer 1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE (1,4-NAPHTHOQUINONE)PALLADIUM(0) DIMER
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