(-)-1,4-DI-O-TOSYL-2,3-O-ISOPROPYLIDENETHREITOL

(-)-1,4-DI-O-TOSYL-2,3-O-ISOPROPYLIDENETHREITOL Basic information
Product Name:(-)-1,4-DI-O-TOSYL-2,3-O-ISOPROPYLIDENETHREITOL
Synonyms:trans-(-)-1,4-Di-O-tosyl-2,3-O-isopropylidene-L-threitol,97%;(2S,3S)-1,4-Di-O-tosyl-2,3-O-isopropylidene-L-threitol;(4S,5S)-(+)-O-ISOPROPYLIDENE-2,3-DIHYDROXY-1,4-BIS(P-TOSYL)BUTANE;(4S,5S)-(-)-4,5-BIS(TOSYLOXYMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE;(4S,5S)-4,5-BIS(TOSYLOXYMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE;(4R,5R)-(-)-O-ISOPROPYLIDENE-2,3-DIHYDROXY-1,4-BIS(P-TOSYL)BUTANE;(-)-1,4-Ditosyl-2,3,O-isopropylidene-L-threitol;(-)-2,3-O-Isopropylidene-1,4-di-O-tosyl-L-threitol
CAS:37002-45-2
MF:C21H26O8S2
MW:470.56
EINECS:253-306-3
Product Categories:organic compound;Biochemistry;Dioxanes & Dioxolanes;Dioxolanes;O-Substituted Sugars;Sugar Alcohols;Sugars
Mol File:37002-45-2.mol
(-)-1,4-DI-O-TOSYL-2,3-O-ISOPROPYLIDENETHREITOL Structure
(-)-1,4-DI-O-TOSYL-2,3-O-ISOPROPYLIDENETHREITOL Chemical Properties
Melting point 90-92 °C(lit.)
Boiling point 542.03°C (rough estimate)
density 1.3082 (rough estimate)
refractive index 1.6000 (estimate)
storage temp. Sealed in dry,2-8°C
solubility DCM, Ethyl Acetate
form Powder
color white
optical activity[α]23/D 12.3°, c = 8.8 in chloroform
BRN 99610
Stability:store cold
CAS DataBase Reference37002-45-2(CAS DataBase Reference)
Safety Information
Safety Statements 24/25
WGK Germany 3
HS Code 2932.99.7000
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
(-)-1,4-DI-O-TOSYL-2,3-O-ISOPROPYLIDENETHREITOL Usage And Synthesis
Chemical Propertieswhite to cream crystalline powder
Uses1,4-Di-O-tosyl-2,3-O-isopropylidene-L-threitol has been used in coordination chemistry of (R,R)-DIPPOP.
(-)-1,4-DI-O-TOSYL-2,3-O-ISOPROPYLIDENETHREITOL Preparation Products And Raw materials
ETHANOL:ISOPROPANOL 19:1, FOR MOLECULAR BIOLOGY (R)-1,4-DITOSYLOXY-2-BUTANOL (S)-(+)-1,3-BUTANEDIOL (-)-1,4-DI-O-TOSYL-2,3-O-ISOPROPYLIDENETHREITOL 1,3-Dioxolane-4-methanol (R)-(+)-1,2,4-BUTANETRIOL 2,4-DIMETHYL, 1,3-DIOXALONE N-BUTYL METHANESULPHONATE 2,2,4-TRIMETHYL-1,3-DIOXOLANE 3-Ethoxy-1-propanol 1,4-Butanediol SEC-BUTYL ETHYL ETHER 2-ETHOXYETHYL P-TOLUENESULFONATE 1,3-Propanediol Ethyl p-toluenesulfonate 1,3-Butanediol (-)-2,3-O-ISOPROPYLIDENE-L-THREITOL 1,4-DIMETHANE SULFONATE Dimethoxymethane

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