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| | Isopentyl formate Basic information |
| | Isopentyl formate Chemical Properties |
| Hazard Codes | Xi | | Risk Statements | 10-36/37 | | Safety Statements | 24-2 | | RIDADR | UN 1109 3/PG 3 | | WGK Germany | 1 | | RTECS | NT0185000 | | HazardClass | 3.2 | | PackingGroup | III | | HS Code | 29151300 | | Toxicity | LD50 orally in rats: 9840 mg/kg, P. M. Jenner et al., Food Cosmet. Toxicol. 2, 327 (1964) |
| | Isopentyl formate Usage And Synthesis |
| Description | Isoamyl formate has a fruity, characteristic odor suggestive of
black currant and plum with a corresponding sweet taste. May be
prepared by reacting concentrated H2S04 over a mixture of
isoamyl alcohols and sodium formate. | | Chemical Properties | Colorless liquid; fruity odor.Partially soluble in water; soluble in
alcohol and ether. Combustible. | | Chemical Properties | Isoamyl formate has a plum, fruity characteristic odor suggestive of black currant, with a corresponding sweet taste.
| | Occurrence | Reported found in apple, pineapple, strawberry, vinegar, Gruyere cheese, chicken fat, beer, cognac, rum, cider,
port wine, tea, honey, avocado, plumcot, mango, quince and sea buckthorn (Hippophae rhamnoides L.) | | Uses | Artificial fruit syrups. | | Uses | Isoamyl Formate is a synthetic flavoring agent that is a moderately stable, colorless to light yellow liquid of pungent pear-plum odor, being soluble in most fixed oils, mineral oil, and propylene glycol. Storage should be in a glass or tin container. It is used in fruit flavors such as pear, plum, and peach for application in dessert gels, puddings, candy, and ice cream at 14–28 ppm.
| | Definition | ChEBI: The formate ester of isoamylol. | | Preparation | By reacting concentrated H2SO4 over a mixture of isoamyl alcohols and sodium formate.
| | Taste threshold values | Taste characteristics at 15 ppm: sharp green, apple and fruity with winey, fatty notes | | Hazard | Strong irritant. | | Purification Methods | The colourless liquid ester is soluble in 300 volumes of H2O and is soluble in common organic solvents. It is purified by repeated distillation using an efficient column at atmospheric pressure. [Beilstein 2 H 22, 2 I 18, 2 II 31, 2 III 43, 2 IV 30.] |
| | Isopentyl formate Preparation Products And Raw materials |
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